Research Publications
279. “Catalytic Prenyl Conjugate Additions for Synthesis of Enantiomerically Enriched PPAPs” S. Ng, C. Howshall, T. N. Ho, B. K. Mai, Y. Zhou, C. Qin, K. Z. Tee, P. Liu, F. Romiti, A. H. Hoveyda Science 2024, 386, 167.
278. “Synthesis of Z-gem-Cl,CF3-Substituted Alkenes by Stereoselective Cross-Metathesis and the Role of Disubstituted Mo Alkylidenes” Q. Liu, C. Qin, J. Wan, B. K. Mai, X. Z. Sui, H. Kobayashi, H. Zahedian, P. Liu, A. H. Hoveyda J. Am. Chem. Soc. 2024, 146, 22485.
277. “A catalytic process enables efficient and programmable access to precisely altered indole alkaloid scaffolds” Y. Huang, X. Li, B. K. Mai, E. J. Tonogai, A. J. Smith, P. J. Hergenrother, P. Liu, A. H. Hoveyda Nat. Chem. 2024, 16, 1003.
276. “Click processes orthogonal to CuAAC and SuFEx forge selectively modifiable fluorescent linkers” P. H. S. Paioti, K. E. Lounsbury, F. Romiti, M. Formica, V. Bauer, C. Zandonella, M. E. Hackey, J. del Pozo, A. H. Hoveyda Nat. Chem. 2024, 16, 426.
275. “Catalytic Cross-Metathesis Reactions That Afford E‑ and Z‑Trisubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights” T. Koengeter, C. Qin, B. K. Mai, Q. Liu, Y. Mu, P. Liu, A. H. Hoveyda J. Am. Chem. Soc. 2023, 145, 3774.
274. “Z-Trisubstituted α,β-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis” C. Qin, T. Koengeter, F. Zhao, Y. Mu, F. Liu, K. N. Houk, A. H. Hoveyda J. Am. Chem. Soc. 2023, 145, 3748.
273. “Diastereo- and enantioselective synthesis of compounds with a trifluoromethyl- and fluoro-substituted carbon centre” S. Xu, J. del Pozo, F. Romiti, Y. Fu, B. K. Mai, R. J. Morrison, K. Lee, S. Hu, M. J. Koh, J. Lee, X. Li, P. Liu, A. H. Hoveyda Nat. Chem. 2022, 14, 1459.
272. “E- and Z-trisubstituted macrocyclic alkenes for natural product synthesis and skeletal editing” Y. Mu, F. W. W. Hartrampf, E. C. Yu, K. E. Lounsbury, R. R. Schrock, F. Romiti, A. H. Hoveyda Nat. Chem. 2022, 14, 640.
271. “Stereodefined Alkenes with a Fluoro-chloro Terminus as a Uniquely Enabling Compound Class” Q. Liu, Y. Mu, T. Koengeter, R. R. Schrock, A. H. Hoveyda Nat. Chem. 2022, 14, 463.
270. “Cross-metathesis of Allenes. Mechanistic Analysis and Identification of a Ru-CAAC as the Most Effective Catalyst” S. A. Gonsales, Z. C. Mueller, F. Zhao, P. H. S. Paioti, L. Karmazin, J. Wan, F. Liu, K. N. Houk, A. H. Hoveyda J. Am. Chem. Soc. 2021, 143, 20640.
269. “Oxo 2-Adamantylidene Complexes of Mo(VI) and W(VI)” M. Boudjelel, F. Zhai, R. R. Schrock, A. H. Hoveyda, C. Tsay Organometallics 2021, 40, 838.
268. “Boosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand σ Donation” J. De Jesus Silva, M. Pucino, F. Zhai, D. Mance, Z. J. Berkson, D. F. Nater, A. H. Hoveyda, C. Copéret, R. R. Schrock Inorg. Chem. 2021, 60, 6875.
267. “Streamlined Catalytic Enantioselective Synthesis of α-Substituted β,γ-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers” J. del Pozo, S. Zhang, F. Romiti, S. Xu, R. P. Conger, A. H. Hoveyda J. Am. Chem. Soc. 2020, 142, 18200.
266. “Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes” F. Zhai, R. R. Schrock, A. H. Hoveyda, P. Müller Organometallics 2020, 39, 2486.
265. “Sulfonate N‐Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C−C, C−B, C−H, and C−Si Bonds” A. H. Hoveyda, Y. Zhou, Y. Shi, M. K. Brown, H. Wu, S. Torker Angew. Chem. Int. Ed. 2020, 59, 21304.
264. “Regio‐ and Enantioselective Synthesis of Trifluoromethyl‐Substituted Homoallylic α‐Tertiary NH2‐Amines by Reactions Facilitated by a Threonine‐Based Boron‐Containing Catalyst” D. C. Fager, R. J. Morrison, A. H. Hoveyda Angew. Chem. Int. Ed. 2020, 59, 11448.
263. “A Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing Z-Alkenyl Chloride or Trifluoromethyl Group. A Protecting Group-Free Synthesis of Mycothiazole” R. J. Morrison, F. W. van der Mei, F. Romiti, A. H. Hoveyda J. Am. Chem. Soc. 2020, 142, 436.
262. “Catalytic Enantioselective Conjugate Addition of Stereodefined Di- and Trisubstituted Alkenylaluminum Compounds to Acyclic Enones” K. P. McGrath, A. K. Hubbell, Y. Zhou, D. P.Santos, S. Torker, F. Romiti, A. H. Hoveyda Adv. Synth. Catal. 2020, 362, 370. (Special issue dedicated to the sixtieth birthday of Professor Eric N. Jacobsen)
261. “Catalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu−F β‑Elimination” P. H. S. Paioti, J. del Pozo, M. S. Mikus, J. Lee, M. J. Koh, F. Romiti, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 19917.
260. “Catalytic Enantioselective Addition of an Allyl Group to Ketones Containing a Tri-, a Di-, or a Monohalomethyl Moiety. Stereochemical Control Based on Distinctive Electronic and Steric Attributes of C–Cl, C–Br, and C–F Bonds” D. C. Fager, K. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 16125.
259. “Copper–Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis” Y. Sun, Y. Zhou, Y. Shi, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141,12087.
258. “Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F-Substituted Stereogenic Quaternary Center” S. Akiyama, K. Kubota, M. S. Mikus, P. H. S. Paioti, F. Romiti, Q. Liu, Y. Zhou, A. H. Hoveyda, H. Ito Angew. Chem. Int. Ed. 2019, 58, 11998.
257. “Silica‐Supported Molybdenum‐Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis” M. Pucino, F. Zhai, C. P. Gordon, D. Mance, A. H. Hoveyda, R. R. Schrock, C. Copéret Angew. Chem. Int. Ed. 2019, 58, 11816.
256. “Ru-Based Catechothiolate Complexes Bearing an Unstaturated NHC Ligand: Effective Cross-Metathesis Catalysts for Synthesis of (Z)-α,β-Unsaturated Esters, Caboxylic Acids and Primary, Secondary, and Weinreb Amides” Z. Liu, C. Xu, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 7137.
255. “E– and Z-, Di- and Tri-Substituted Alkenyl Nitriles Through Catalytic Cross-Metathesis” Y. Mu, T. Nguyen, M.J. Koh, R. R. Schrock, A. H. Hoveyda Nat. Chem. 2019, 11, 478.
254. “Delayed Catalyst Function Enables Direct Enantioselective Conversion of Nitriles to NH2-Amines” S. Zhang, J. del Pozo, F. Romiti, Y. Mu, S. Torker, A. H. Hoveyda Science 2019, 364, 45.
253. “Traceless Protection for More Broadly Applicable Olefin Metathesis” Y. Mu, T. Nguyen, F. W. van der Mei, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2019, 58, 5365.
252. “Racemic Vinylallenes in Catalytic Enantioselective Mutlicomponent Processes. Rapid Generation of Complexity through 1,6-Conjugate Additions” Y. Huang, S. Torker, X. Li, J. del Pozo, A. H. Hoveyda Angew. Chem. Int. Ed. 2019, 58, 2685.
251. “SN2″-Selective and Enantioselective Substitution with Unsaturated Organoboron Compounds and Catalyzed by a Sulfonate-Containing NHC-Cu Complex” Y. Zhou, Y. Shi, S. Torker, and A. H. Hoveyda J. Am. Chem. Soc. 2018, 140, 16842.
250. “Syntheses of Molybendenum Oxo Benzylidene Complexes” F. Zhai, K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. Müller J. Am. Chem. Soc. 2018, 140, 13609.
249. “γ-, Diastereo-, and Enantioselective Addition of MEMO-Substituted Allylboron Compounds to Aldimines Catalyzed by Organoboron-Ammonium Complexes” R. J. Morrison, A. H. Hoveyda Angew. Chem. Int. Ed. 2018, 57, 11654.
248. “Syntheses of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN” S. VenkatRamani, R.R. Schrock, A. H. Hoveyda, P. Müller, C. Tsay Organometallics 2018, 37, 1641.
247. “Syntheses of Molybendenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex” K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. Müller J. Am. Chem. Soc. 2018, 140, 2797.
246. “Enantioselective Synthesis for Trisubstituted Allenyl—B(pin) Compounds by Phosphine—Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Intergrity of Cu—Allenyl Intermediates” Y. Huang, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2018, 140, 2643.
245. “Mechanism-based Enhancement of Scope and Enantioselectivity for Reactions Involving a Copper-Substituted Stereogenic Carbon Centre” J. Lee, S. Radomkit, S. Torker, J. del Pozo, A. H. Hoveyda Nat. Chem. 2018, 10, 99.
244. “Synthesis of E-and Z-Trisubstituted Alkenes by Catalytic Cross-Metathesis” T. T. Nguyen, M. J. Koh, T. J. Mann, R. R. Schrock, A. H. Hoveyda Nature 2017, 552, 347.
243. “Synthesis of Z– or E-Trisubstituted Allylic Alcohols and Ethers by Kinetically Controlled Cross-Metathesis with a Ru Catechothiolate Complex” C. Xu, Z. Liu, S. Torker, X. Shen, D. Xu, A.H. Hoveyda J. Am. Chem. Soc. 2017, 139, 15640.
242. “Synthesis of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCl and Diphenylmenthylphosphine” K. V. Bukhryakov, S. VenkatRamani, C. Tsay, A. Hoveyda, R. R. Schrock Organometallics 2017, 36, 4208.
241. “Enantioselective Total Synthesis of (—)-Deoxoapodine” T. Kang, K. L. White, T. J. Mann, A. H. Hoveyda, M. Movassaghi Angew. Chem. Int. Ed. 2017, 56, 13857.
240. “In Situ Methylene Capping: A General Strategy for Efficient Stereoretentive Catalytic Olefin Metathesis. The Concept, Methodological Implications, and Applications to Synthesis of Biologically Active Compounds” C. Xu, X. Shen, A. H. Hoveyda J. Am. Chem. Soc. 2017, 139, 10919.
239. “Catalytic Diastereo- and Enantioselective Additions of Versatile Allyl Groups to N-H Ketimines,“ H. Jang, F. Romiti, S. Torker, A. H. Hoveyda Nat. Chem. 2017, 9, 1269.
238. “Practical, Broadly Applicable, α- Selective, Z-Selective, Diastereoselective and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri- and Polyfluoroalkyl Ketones,“ F. W. van der Mei, C. Qin, R. J. Morrison, A. H. Hoveyda J. Am. Chem. Soc. 2017, 139, 9053.
237. “Practical, Efficient, and Broadly Applicable Synthesis of Readily Differentiable Vicinal Diboronate Compounds by Catalytic Three-Component Reactions,“ S. Radomkit, Z. Liu, A. Closs, M.S. Mikus, A. H. HoveydaTetrahedron, 2017, 73, 5011. (Special issue in honor of Professor Ben Feringa)
236. “Electronically Activated Organoboron Catalysts for Enantioselective Propargyl Addition to Trifluoromethyl Ketones,“ N.W. Mszar, M. S. Mikus, S. Torker, F. Haeffner, A. H. Hoveyda Angew. Chem. Int. Ed. 2017, 56, 8736.
235. “Synthesis of 2,6,-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X + I, Li, OH, SH, N3, or NH2,“ K.V. Bukhryakov, R. R. Schrock, A. H. Hoveyda, P. Müller, J. Becker Org. Lett. 2017, 19, 2607.
234. “Molybdenum Chloride Catalysts for Z-Selective Olefin Metathesis Reactions,“ M. J. Koh, T. T. Nguyen, J. K. Lam, S. Torker, J. Hyvl, R. R. Schrock, A. H. Hoveyda Nature 2017, 542, 80.
233. “Kinetically E-Selective Macrocyclic Ring-Closing Metathesis,“ X. Shen, T. T. Nguyen, M. J. Koh, D. Xu, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda Nature 2017, 541, 380.
232. “Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioslective Catalytic Sequence of Cu—H Addition to Vinyl-B(pin)/Allylic Substitution,” J. Lee, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2017, 56, 821.
231. “Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene,” J. Lam, C. Zhu, K. V. Bukhryakov, P. Müller, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 2016, 138, 15774.
230. “Pentacoordinate Ruthenium(ll) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation,” M. S. Mikus, S. Torker, C. Xu, B. Li, A. H. Hoveyda Organometallics 2016, 35, 3878.
229. “Synthesis of Linear (Z)- α , β -Unsaturated Esters by Catalytic Crosss-Metathesis. The Influence of Acetonitrile,” E. C. Yu, B. M. Johnson, E. M. Townsend, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 13210.
228. “Catalytic Enantioselective 1,6-Conjugate Additions of Propargyl and Allyl Groups,” F. Meng, X. Li, S. Torker, Y. Shi, X. Shen, A. H. Hoveyda Nature 2016, 537, 387.
227. “Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene,” X. Li, F. Meng, S. Torker, Y. Shi, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 9997.
226. “Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl–B(pin) Compounds to Ketones and α -Ketoesters,” D. W. Robbins, K. Lee, D. L. Silverio, A. Volkov, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 9610.
225. “Catalytic Enantioselective Addition of Organoboron Reagents to Fluoroketones Controlled by Electrostatic Interactions,” K. Lee, D. L. Silverio, S. Torker, F. Haeffner, D. W. Robbins, F. W. van der Mei, A. H. Hoveyda Nat. Chem. 2016, 8, 768.
224. “Kinetically controlled E-Selective Catalytic Olefin Metathesis,” T. T. Nguyen, M. J. Koh, X. Shen, F. Romiti, R. R. Schrock, A. H. Hoveyda Science 2016, 352, 569.
223. “Controllable ROMP Tacticity by Harnessing the Fluxionality of Stereogenic-at-Ruthenium Complexes,“ M. S. Mikus, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 4997.
222. “Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective γ-Additions of Allylboron Moieties to Aldimines,” F. W. van der Mei, H. Miyamoto, D. L. Silverio, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 4701.
221. “Catalytic SN2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis,” Y. Shi, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 3455.
220. “Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Methathesis,” M. J. Koh, T. T. Nguyen, H. Zhang, R. R. Schrock, A. H. Hoveyda Nature 2016, 531, 459.
219. “Regarding a Persisting Puzzle in Olefin Metathesis with Ru Complexes: Why are Transformations of Alkenes with a Small Substituent Z-Selective?,” S. Torker, M. J. Koh, R. K. Khan, A. H. Hoveyda Organometallics 2016, 35, 543.
218. “Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to β Unsaturated Carbonyl Compounds” H. Wu, J. M. Garcia, F. Haeffner, S. Radomkit, A. R. Zhugralin, A. H. Hoveyda J. Am. Chem. Soc. 2015, 137, 10585.
217. “N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes,” Y. Shi , B. Jung , S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2015, 137, 8948.
216. “N-Substituted Tertiary and O-Substituted Quaternary Carbon Stereogenic Centers by Site-, Diastereo- and Enantioselective Vinylogous Mannich Reactions,” D. L. Silverio, P. Fu, E. L. Carswell, M. L. Snapper, A. H. Hoveyda Tetrahedron Lett. 2015, 56, 3489. (Special issue in memory of Professor Harry H. Wasserman)
215. “Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand,” J. C. Axtell, R. R. Schrock, Peter Müller, A. H. Hoveyda Organometallics 2015, 34, 2110.
214. “Synthesis of Alternating trans-AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes,” H. Jeong, J. M. John, R. R. Schrock, A. H. HoveydaJ. Am. Chem. Soc. 2015, 137, 2239.
213. “High-Value Alcohols and Higher-Oxidation-State Compounds by Catalytic Z-Selective Cross-Metathesis,” M. J. Koh, R. K. M. Khan, S. Torker, M. Yu, M. S. Mikus, A. H. Hoveyda Nature 2015, 517, 181.
212. “Catalyst-Controlled Stereoselective Olefin Metathesis as a Principal Strategy in Multistep Synthesis Design: A Concise Route to (+)-Neopeltolide,” M. Yu, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2015, 54, 215.
211. “Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis,” H. Zhang, E. C. Yu, S. Torker, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 16493.
210. “Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1,” A. W. H. Speed, T. J. Mann, R. V. O’Brien, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 16136.
209. “Reactivity and Selectivity Differences between Catecholate and Catechothiolate Ru Complexes. Implications Regarding Design of Stereoselective Olefin Metathesis Catalysts,” R. K. M. Khan, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 14337.
208. “Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands,” E. M. Townsend, J. Hyvl, W. P. Forrest, R. R. Schrock, P. Müller, A. H. Hoveyda Organometallics 2014, 33, 5334.
207. “Multifunctional Organoboron Compounds for Scalable Natural Product Synthesis,” F. Meng, K. P. McGrath, A. H. Hoveyda Nature 2014, 513, 367.
206. “Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand,” J. C. Axtell, R. R. Schrock, P. Müller, S. J. Smith, A. H. Hoveyda Organometallics 2014, 33, 5342.
205. “Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity,” H. Jang, B. Jung, A. H. Hoveyda Org. Lett. 2014, 16, 4658.
204. “Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex,” F. Meng, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 11304.
203. “Synthesis of (±)-Tetrapetalone A-Me Aglycon,” P. N. Carlsen, T. J. Mann, A. H. Hoveyda, A. J. Frontier Angew. Chem. Int. Ed. 2014, 53, 9334.
202. “An Efficient, Practical, and Enantioselective Method for Synthesis of Homoallenylamides Catalyzed by an Aminoalcohol-Derived, Boron-Based Catalyst,” H. Wu, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3780.
201. “NHC–Cu-Catalyzed Addition of Propargylboron Reagents to Phosphinoylimines. Enantioselective Synthesis of Trimethylsilyl-Substituted Homoallenylamides and Application to the Synthesis of S-(–)-Cyclooroidin,” N. W. Mszar, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3362.
200. “The Influence of Anionic Ligands on Stereoisomerism of Ru Carbenes and Their Importance to Efficiency and Selectivity of Catalytic Olefin Metathesis Reactions,” S. Torker, R. K. M. Khan, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3439.
199. “Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones,” S. Radomkit, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53, 3387.
198. “A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis,” F. Gao, J. L. Carr, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 2149.
197. “Broadly Applicable Z– and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex,” M. J. Koh, R. K. M. Khan, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53, 1968.
196. “A Multicomponent Ni-, Zr-, and Cu-Catalyzed Strategy for Enantioselective Synthesis of Alkenyl-Substituted Quaternary Carbons,” K. P. McGrath, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53,1910.
195. “High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes,” E. M. Townsend, S. M. Kilyanek, R. R. Schrock, P.Müller, S. J. Smith, A. H. Hoveyda Organometallics 2013, 32, 4612.
194. “Enantioselective Silyl Protection of Alcohols Promoted by a Combination of Chiral and Achiral Lewis Basic Catalysts,” N. Mannville, H. Alite, F. Haeffner, A. H. Hoveyda, M. L. Snapper Nat. Chem. 2013, 5, 768.
193. “Catalytic Z-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis,” T. J. Mann, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 8395.
192. “Readily Accessible and Easily Modifiable Ru-Based Catalysts for Efficient and Z-Selective Ring-Opening Metathesis Polymerization and Ring-Opening/Cross-Metathesis,” R. K. M. Khan, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2013, 135, 10258.
191. “Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Cu-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones,” J. A. Dabrowski, M. T. Villaume, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 8156.
190. “Combining NHC–Cu and BØnsted Base Catalysis: Enantioselective Allylic Substitition/Conjugate Addition with Alkynyllithium Reagents and Stereospecific Isomerization of Products to Trisubstituted Allenes,” J. A. Dabrowski, J. Haeffner, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 7694.
189. “Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis,” E. T. Kiesewetter, R. V. O’Brien, E. C. Yu, S. J. Meek, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2013, 135, 6026.
188. “Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones,” F. Meng, H. Jang, B. Jung, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 5046.
187. “NHC-Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism,” F. Meng, B. Jung, F. Haeffner, A. H. Hoveyda Org. Lett. 2013, 15, 1414.
186. “Simple Organic Molecules as Catalysts for Enantioselective Synthesis of Amines and Alcohols,” D. Silverio, S. Torker, T. Pilyugina, E. M. Vieira, M. L. Snapper, F. Haeffner, A. H. Hoveyda Nature 2013, 494, 216.
185. “Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total syntheses of Epilachnene, Yuzu Lactone, Ambrettolide, Epothilone C, and Nakadomarin A,” C. Wang, M. Yu, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda Chem. Eur. J. 2013, 19, 2726.
184. “Exceptionally E– and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes,” F. Meng, H. Jang, A. H. Hoveyda Chem. Eur. J. 2013, 19, 3204.
183. “Molybdenum-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysis for Efficient Z-selective Synthesis of a Macrocylic Trisubstituted Alkene by Ring Closing Metathesis,” C. Wang, F. Haeffner, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 1939.
182. “NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes,” K.-S. Lee, H. Wu, F. Haeffner, A. H. Hoveyda Organometallics 2012, 31, 7823.
181. “Z– and Enantioselective Ring-Opening/Cross-Metathesis with Enol Ethers Catalyzed by Stereogenic-at-Ru Carbenes: Reactivity, Selectivity, and Curtin-Hammett Kinetics,” R. K. M. Khan, R. V. O’Brien, S. Torker, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 12774.
180. “Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways,” R. K. M. Khan, A. R. Zhugralin, S. Torker, R. V. O’Brien, P. J. Lombardi, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 12438.
179. “Z-selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes,” E. M. Townsend, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 11334.
178. “Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes,” A. G. Lichtscheidl, V. W. L. Ng, P. Müller, M. K. Takase, R. R. Schrock, S. J. Malcolmson, S. J. Meek, B. Li, E. T. Kiesewetter, A. H. Hoveyda Organometallics 2012, 31, 4558.
177. “Cu-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents,” F. Gao, J. L. Carr, A. H. Hoveyda Angew. Chem. Int. Ed. 2012, 51, 6613.
176. “A Robust, Efficient and Highly Enantioselective Method for Synthesis of Homopropargyl Amines,” E. M. Vieira, F. Haeffner, M. L. Snapper, A. H. Hoveyda Angew. Chem. Int. Ed. 2012, 51, 6618.
175. “Metal-Free Catalytic Enantioselective C-B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes,” H. Wu, S. Radomkit, J. M. O’Brien, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 8277.
174. “Enol Ethers as Substrates for Efficient Z– and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes,” M. Yu, I. Ibrahem, M. Hasegawa, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 2788.
173. “Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution,” B. Jung, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 1490.
172. “Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes,” D. V. Peryshkov, R. R. Schrock, M. K. Takase, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 20754.
171. “Synthesis of Macrocyclic Natural Products by Catalyst-Controlled Stereoselective Ring-Closing Metathesis,” M. Yu, C. Wang, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda Nature 2011, 479, 88.
170. “Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures,” S. C. Marinescu, D. S. Levine, Y. Zhao, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 11512.
169. “Regiodivergent Reactions through Catalytic Enantioselective Silylation of Chiral Diols. Synthesis of Sapinofuranone A,” J. M. Rodrigo, Y. Zhao, A. H. Hoveyda, M. L. Snapper Org. Lett. 2011, 13, 3778.
168. “NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes,” R. Corberan, N. W. Mszar, A. H. Hoveyda Angew. Chem. Int. Ed. 2011, 50, 7079.
167. “Metal-Free Catalytic C-Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls,” J. M. O’Brien, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 7712.
166. “Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC-Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity,” H. Jang, A. R. Zhugralin, Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 7859.
165. “Room-Temperature Z-Selective Homocoupling of α-Olefins by Tungsten Catalysts,” S. C. Marinescu, R. R. Schrock, P. Müller, M. K. Takase, A. H. Hoveyda Organometallics 2011, 30, 1780.
164. “Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents,” J. A. Dabrowski, F. Gao, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 4778.
163. “Catalytic Z-Selective Olefin Cross-Metathesis for Natural Product Synthesis,” S. J. Meek, R. V. O’Brien, J. Llaveria, R. R. Schrock, A. H. Hoveyda Nature 2011, 471, 461.
162. “Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl- or Alkene-Substituted Aldimines Catalyzed by Chiral C-Symmetric NHC-Cu-Complexes,” E. M. Vieira, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 3332.
161. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes,” Y. Zhao, A. H. Hoveyda, R. R. Schrock Org. Lett. 2011, 13, 784.
160. “Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones,” T. L. May, J. A. Dabrowski, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 736.
159. “Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinyaluminum Reagents,” F. Gao, K. P. McGrath, Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 14315.
158. “Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Hetero-aryllithium Reagents and Aluminum Chlorides,” F. Gao, Y. Lee, K. Mandai, A. H. Hoveyda Angew. Chem., Int. Ed. 2010, 49, 8370.
157. “α -Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes. Practical Syntheses of Internal Vinyl Aluminums, Halides or Boronates,” F. Gao, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 10961.
155. “Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions,” A. Guzman-Martinez, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 10634.
154. “Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes,” K.-S. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 2898.
153. “Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Cu-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E alkenes,” K. Akiyama, F. Gao, A. H. Hoveyda Angew. Chem., Int. Ed. 2010, 49, 419.
152. “Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC-Cu-Catalyzed Boron-Copper Additions to Terminal Alkynes,” Y. Lee, H. Jang, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 18234.
151. “Highly Z-Selective Metathesis Homocoupling of Terminal Olefins,” A. J. Jiang, Y. Zhao, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 16630.
150. “The Significance of Degenerate Processes to Enantioselective Olefin Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes,” S. J. Meek, S. J. Malcolmson, B. Li, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 16407.
149. “Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,” S. C. Marinescu, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 10840.
148. “Stereogenic-at-Metal Zn- and Al-based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations,” Y. Lee, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 11625.
147. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-Mo Monoalkoxide and Monoaryloxide Complexes. Efficient Synthesis of Cyclic Dienes Not Accessible through Reactions with Ru Carbenes,” Y.-J. Lee, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 10652.
146. “H-Bonding as an Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis,” A. H. Hoveyda, P. J. Lombardi, R. V. O’Brien, A. R. Zhugralin J. Am. Chem. Soc. 2009, 131, 8378.
145. “Z-Selective Olefin Metathesis Processes Catalyzed by a Molybdenum Hexaisopropylterphenoxide Monopyrrolide Complex,” M. M. Flook, A. J. Jiang, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 7962.
144. “Monodentate Non-C2-Symmetric Chiral N-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones,” K.-S. Lee, A. H. Hoveyda J. Org. Chem. 2009, 74, 4455.
143. “Efficient C-B Bond Formation Promoted by N-Heterocyclic Carbenes. Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls,” K.-S. Lee, A. R. Zhugralin, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 7253.
142. “Efficient Boron-Copper Additions to Aryl-Substituted Alkenes Promoted by NHC-Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions,” Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 3160.
141. “Highly Z– and Enantioselective Ring-Opening/Cross Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes,” I. Ibrahem, M. Yu, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 3844.
140. “Design and Stereoselective Preparation of a New Class of Chiral Olefin Metathesis Catalysts and Application to Enantioselective Synthesis of Quebrachamine. Catalyst Development Inspired by Natural Product Synthesis,” E. S. Sattely, S. J. Meek, S. J. Malcolmson, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 943.
139. “Inversion of Configuration at the Metal in Diastereomeric Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,” S. C. Marinescu, R. R. Schrock, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 58.
138. “Enantioselective Synthesis of P-Stereogenic Phosphinates and Phosphine Oxides by Mo-Catalyzed Asymmetric Ring-Closing Metathesis,” J. S. Harvey, S. J. Malcolmson, K. S. Dunne, S. J. Meek, A. L. Thompson, R. R. Schrock, A. H. Hoveyda, V. Gouverneur Angew. Chem., Int. Ed. 2009, 48, 762.
137. “Catalytic Enantioselective Silylation of Acyclic and Cyclic Triols and Application to Total Syntheses of Cleroindicins D, F, and C,” Z. You, A. H. Hoveyda, M. L. Snapper Angew. Chem., Int. Ed. 2009, 48, 547.
136. “Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism,” L. C. Wieland, E. M. Vieira, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 570.
135. “Three-Component Ag-Catalyzed Enantioselective Vinylogous Mannich and Aza-Diels-Alder Reactions with Alkyl-Substituted Aldehydes,” H. Mandai, K. Mandai, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 17961.
134. “Highly Efficient Molybdenum-Based Catalysts for Enantioselective Alkene Metathesis,” S. J. Malcolmson, S. J. Meek, E. S. Sattely, R. R, Schrock, A. H. Hoveyda Nature 2008, 456, 933.
133. “Enantioselective Total Synthesis of Clavirolide C. Applications of Cu-Catalyzed Asymmetric Conjugate Additions and Ru-Catalyzed Ring-Closing Methathesis,” M. K. Brown, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 12904.
132. “Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones,” T. L. May, M. K. Brown, A. H. Hoveyda Angew. Chem., Int. Ed. 2008, 47, 7358.
131. “Aluminum-Catalyzed Asymmetric Alkylations of Pyridyl-Substituted Alkynyl Ketones with Dialkylzinc Reagents,” D. K. Friel, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 9942.
130. “Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis of N-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl- and Trifluoroalkyl-Substituted Ketoimines,” P. Fu, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 5530.
129. “Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents,” Y. Lee, K. Akiyama, D. Gillingham, M. K. Brown, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 446.
128. “Kinetic Resolution of 1,2-Diols through Highly Site- and Enantioselective Catalytic Silylation,” Y. Zhao, A. W. Mitra, A. H. Hoveyda, M. L. Snapper Angew. Chem., Int. Ed. 2007, 46, 8471.
127. “Synthesis of Monoalkoxide Monopyrrolyl Complexes of the Type Mo(NR)(CHR’)(OR”)(pyrrolyl). Enyne Metathesis with High Oxidation State Catalysts,” R. Singh, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2007, 129, 12654.
126. “Cu-Catalyzed Asymmetric Conjugate Additions of Dialkyl- and Diarylzinc Reagents to Acyclic β-Silyl-α , β-Unsaturated Ketones. Synthesis of Allylsilanes in High Diastereo- and Enantiomeric Purity,” M. A. Kacprzynski, S. A. Kazane, T. L. May, A. H. Hoveyda Org. Lett. 2007, 9, 3187.
125. “Comparison of Ru- and Mo- Based Chiral Olefin Metathesis Catalysts. Complementarity in Asymmetric Ring-Opening/Cross-Metathesis Reactions of Oxa- and Azabicycles,” G. A. Cortez, C. A. Baxter, R. R. Schrock, A. H. Hoveyda Org. Lett. 2007, 9, 2871.
124. “Molybdenum Imido Alkylidene Metathesis Catalysts That Contain Electron-Withdrawing Biphenolates or Binaphtholates,” R. Singh, C. Czekelius, R. R. Schrock, P. M. Müller, A. H. Hoveyda Organometallics 2007, 26, 2528.
122. “Efficient Enantioselective Synthesis of Piperidines through Catalytic Asymmetric Ring-Opening/Cross Metathesis Reactions,” G. A. Cortez, R. R. Schrock, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 4534.
121. “Directed Catalytic Asymmetric Olefin Metathesis. Selectivity Control by Enoate and Ynoate Groups in Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis,” R. E. Guidici, A. H. Hoveyda J. Am. Chem. Soc. 2007, 129, 3824.
120. “Chiral N-Heterocyclic Carbenes in Natural Product Synthesis. Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C,” D. G. Gillingham, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 3860.
119. “New Enantiomerically Pure Alkyimido Molybdenum-Based Alkylidene Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts,” T. S. Pilyugina, R. R. Schrock, P. Müller, A. H. Hoveyda Organometallics 2007, 26, 831.
118. “All-Carbon Quaternary Stereogenic Centers by Enantioselective Cu-Catalyzed Conjugate Additions Promoted by a Chiral N-Heterocyclic Carbene,” M. K. Brown, T. L. May, C. A. Baxter, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 1097.
117. “Dipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,” A. S. Hock, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 16373.
116. “Lewis Base Activation of Grignard Reagents with N-Heterocyclic Carbenes. Cu-Free Catalytic Enantioselective Additions to γ-Chloro α -,β-Unsaturated Esters,” Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 15604.
115. “A Highly Efficient and Practical Method for Catalytic Asymmetric Vinylogous Mannich (AVM) Reactions,” E. L. Carswell, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 2006, 45, 7230.
114. “Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,” A. Sinha, R. R. Schrock, P. Muller, A. H. Hoveyda Organometallics 2006, 25, 4621.
113. “Enantioselective Silyl Protection of Alcohols Catalysed by an Amino Acid-Based Small-Molecule,” Y. Zhao, J. Rodrigo, A. H. Hoveyda, M. L. Snapper Nature 2006, 443, 67.
112. “A Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to β-Substituted Cyclic Enones,” K.-S. Lee, M. K. Brown, A. W. Hird, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 7182.
111. “A Chiral Ag-based Catalyst for Practical, Efficient and Highly Enantioselective Additions of Enolsilanes to α-Ketoesters,” L. C. Akullian, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 6532.
110. “Operationally Simple, Efficient, and Diastereoselective Synthesis of cis-2,6-Disubstituted-4-Methylene Tetrahydropyrans Catalyzed by Triflic Acid,” A. Puglisi, A.-L. Lee, R. R. Schrock, A. H. Hoveyda Org. Lett. 2006, 8, 1871.
109. “Enantioselective Synthesis of Cyclic Enol Ethers and All-Carbon Quaternary Stereogenic Centers through Catalytic Asymmetric Ring-Closing Metathesis,” A.-L. Lee, S. J. Malcolmson, A. Puglisi, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 5153.
108. “Al-Catalyzed Enantioselective Alkylation of α-Ketoesters by Dialkylzinc Reagents. Enhancement of Enantioselectivity and Reactivity by an Achiral Lewis Base Additive,” L. C. Wieland, H. Deng, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 15453.
107. “Catalytic Enantioselective Alkylations of Tetrasubstituted Olefins. Synthesis of All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Enones,” A. W. Hird, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 14988.
106. “Highly Enantioselective Cu-Catalyzed Conjugate Additions of Dialkylzinc Reagents to Unsaturated Furanones and Pyranones: Preparation of Air Stable and Catalytically Active Cu.Peptide Complexes,” M. K. Brown, S. J. Degrado, A. H. Hoveyda Angew. Chem., Int. Ed. 2005, 44, 5306.
105. “Proline-Based N-Oxides as Readily Available and Modular Chiral Catalysts. Enantioselective Reactions of Allyltrichlorosilane with Aldehydes,” J. F. Traverse, Y. Zhao, A. H. Hoveyda, M. L. Snapper Org. Lett. 2005, 7, 3151.
104. “Practical and Highly Enantioselective Synthesis of β-Alkynyl-β-amino Esters through Ag-Catalyzed Asymmetric Mannich Reactions of Silylketene Acetals and Alkynyl Imines,” N. S. Josephsohn, E. L. Carswell, M. L. Snapper, A. H. Hoveyda Org. Lett. 2005, 7, 2711.
103. “Enantioselective Synthesis of Cyclic Amides and Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis,” E. S. Sattely, G. A. Cortez, D. C. Moebius, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 8526.
102. “Isocomplestatin: Total Synthesis and Stereochemical Revision,” T. Shinohara, H. Deng, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 7334.
101. “A Readily Available Chiral Ag-Based N-Heterocyclic Carbene Complex for Use in Efficient and Highly Enantioselective Ru-Catalyzed Olefin Metathesis and Cu-Catalyzed Allylic Alkylation Reactions,” J. J. Van Veldhuizen, J. E. Campbell, R. E. Guidici, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 6877.
100. “Enantioselective Synthesis of Nitroalkanes Bearing All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions,” J. Wu, D. M. Mampreian, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 4584.
99. “Catalytic Enantioselective Synthesis of Quaternary All-Carbon Stereogenic Centers. Preparation of α,α’-Disubstituted-β,γ-Unsaturated Esters through Cu-Catalyzed Asymmetric Allylic Alkylations,” K. E. Murphy, A. H. Hoveyda Org Lett. 2005, 7, 1255.
98. “Asymmetric Synthesis of Acyclic Amines Through Zr- and Hf-Catalyzed Enantioselective Addition of Alkylzinc Reagents to Imines,” L. C. Akullian, J. R. Porter, J. F. Traverse, M. L. Snapper, A. H. Hoveyda Adv. Synth. Catal. 2005, 347, 417.
97. “Regarding the Mechanism of Olefin Metathesis with Sol-Gel-Supported Ru-Based Complexes Bearing a Bidentate Carbene Ligand. Spectroscopic Evidence for Return of the Propagating Ru Carbene,” J. S. Kingsbury, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 4510.
96. “Efficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru-Catalyzed Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM),” D. G. Gillingham, O. Kataoka, S. B. Garber, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 12288.
95. “Bidentate NHC-Based Chiral Ligands for Efficient Cu-Catalyzed Enantioselective Allylic Alkylations: Structure and Activity of an Air-Stable Chiral Cu Complex,” A. O. Larsen, W. Leu, C. N. Oberhuber, J. E. Campbell, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 11130.
94. “Efficient Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Aromatic and Aliphatic Acyclic Nitroalkenes,” D. M. Mampreian, A. H. Hoveyda Org. Lett., 2004, 6, 2829.
93. “Investigations of Reactions between Chiral Molybdenum Imido Alkylidene Complexes and Ethylene: Observation of Unsolvated Base-Free Methylene Complexes, Metalacyclobutane and Metalacyclopentane Complexes, and Molybdenum(IV) Olefin Complexes,” W. C. P. Tsang, J. Y. Jamieson, S. L. Aeilts, K. C. Hultzsch, R. R. Schrock, A. H. Hoveyda Organometallics, 2004, 23, 1997.
92. “Supported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis,” S. J. Dolman, K. C. Hultzsch, F. Pezet, X. Teng, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc., 2004, 126, 10945.
91. “Enantioselective Synthesis of Cyclic Allylboronates by Mo-catalyzed Asymmetric Ring-Closing Metathesis (ARCM). A One-Pot Protocol for Net Catalytic Enantioselective Cross Metathesis,” J. A. Jernelius, R. R. Schrock, A. H. Hoveyda Tetrahedron, 2004, 60, 7345.
90. “Cu-Catalyzed Asymmetric Allylic Alkylations of Aromatic and Aliphatic Phosphates with Alkylzinc Reagents. An Effective Method for Enantioselective Synthesis of Tertiary and Quaternary Carbons, ” M. A. Kacprzynski, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 10676.
89. “Ag-Catalyzed Asymmetric Mannich Reactions of Enol Ethers with Aryl, Alkyl, Alkenyl, and Alkynyl Imines,” N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 3734.
88. “Catalytic Homologation of Vinyltributylstannane to Allyltributylstannae by Mo(IV) Complexes in the Presence of Ethylene,” R. R. Schrock, M. Duval-Lungulescu, W. C. P. Tsang, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 1948.
87. “Mo-Catalyzed Asymmetric Olefin Metathesis in Target-Oriented Synthesis. Enantioselective Synthesis of (+)-Africanol,” G. S. Weatherhead, G. A. Cortez, R. R. Schrock, A. H. Hoveyda Proc. Nat. Acad. Sci. 2004, 101, 5805.
86. “Enantioselective Total Synthesis of Erogorgiaene: Applications of Asymmetric Cu-Catalyzed Conjugate Additions of Alkylzincs to Acyclic Enones,” R. R. Cesati, J. de Armas, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 96.
85. “Enantioselective Synthesis of Cyclic Secondary Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis (ARCM),” S. J. Dolman, R. R. Schrock, A. H. Hoveyda Org. Lett. 2003, 5, 4899.
84. “Chiral Ru-Based Complexes for Asymmetric Olefin Metathesis: Enhancement of Catalytic Activity through Steric and Electronic Modifications”, J. J. Van Veldhuizen, D. G. Gillingham, S. B. Garber, O. Kataoka, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 12502.
83. “Three-Component Enantioselective Synthesis of Propargylamines through Zr-Catalyzed Additions of Alkyl Zinc Reagents to Alkynylimines,” L. C. Akullian, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 2003, 42, 4244.
82. “Enantioselective Synthesis of Propargylamines through Zr-Catalyzed Addition of Mixed Alkynylzinc Reagents to Arylimines,” J. F. Traverse, A. H. Hoveyda, M. L. Snapper Org. Lett. 2003, 5, 3273.
81. “Total Synthesis of Anti-HIV Chloropeptin I,” H. Deng, J-K. Jung, T. Liu, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 9032.
80. “Enantioselective Synthesis of α-Alkyl-β,γ-unsaturated Esters through Efficient Cu-Catalyzed Allylic Alkylations,” K. E. Murphy, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 4690.
79. “Efficient and Practical Ag-Catalyzed Cycloadditions between Arylimines and the Danishefsky Diene,” N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 4018.
78. “Cu-Catalyzed Enantioselective Conjugate Additions of Alkyl Zinc Reagents to Unsaturated N-Acyloxazolidinones Promoted by a Chiral Triamide Phosphane,” A. W. Hird, A. H. Hoveyda Angew. Chem., Int. Ed. 2003, 42, 1276.
77. “An Enantiomerically Pure Adamantylimido Molybdenym Alkylidene Complex. An Effective New Catalyst for Enantioselective Olefin Metathesis,” W. C. P. Tsang, J. A. Jernelius, G. A. Cortez, G. S. Weatherhead, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 2591.
76. “Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations,” W. C. P. Tsang, K. C. Hultzsch, J. B. Alexander, P. J. Bonitatebus, Jr., R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 2652.
75. “Zr-Catalyzed Diastereo- and Enantioselective Diene Cyclizations. An Unexpected Synthesis of Chiral Aldehydes,” S. J. Degrado, J. A. Adams, A. H. Hoveyda Inorg. Chim. Acta 2003, 345, 261.
74. “Efficient Cu-Catalyzed Asymmetric Conjugate Additions of Allylzincs to Trisubstituted Cyclic Enones,” S. J. Degrado, H. Mizutani, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 13362.
73. “Enhancement of Enantioselectivity by THF in Asymmetric Mo-Catalyzed Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Tertiary Ethers and Spirocycles,” X. Teng, D. R. Cefalo, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 10779.
72. “Cu–Catalyzed Enantioselective Conjugate Addition of Alkylzincs to Cyclic Nitroalkenes: Catalytic Asymmetric Synthesis of Cyclic α-Substituted Ketones,” C. A. Luchaco-Cullis, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 8192.
71. “Efficient Catalytic Enantioselective Synthesis of Unsaturated Amines: Preparation of Small- and Medium-Ring Cyclic Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis in the Absence of Solvent,” S. J. Dolman, E. S. Sattely, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 2002, 124, 6991.
70. “A Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring-Opening/Cross Metathesis in Air,” J. J. Van Veldhuizen, S. B. Garber, J. S. Kingsbury, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 4954.
69. “Enantioselective Synthesis of Medium Ring Heterocycles, Tertiary Ethers and Tertiary Alcohols by Mo-Catalyzed Ring-Closing Metathesis,” A. F. Kiely, J. A. Jernelius, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 2868.
68. “Olefins Turned Alkylating Agents: Diastereoselective Intramolecular Zr-Catalyzed Olefin Alkylations,” R. R. Cesati III, J. de Armas, A. H. Hoveyda Org. Lett. 2002, 4, 395.
67. “Aluminum-Catalyzed Asymmetric Addition of TMSCN to Aromatic and Aliphatic Ketones Promoted by an Easily Accessible and Recyclable Peptide Ligand,” H. Deng, M. P. Isler, M. L. Snapper, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20020315)41:63.0.CO;2-F”>Angew. Chem., Int. Ed. 2002, 41, 1009.
66. “The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis,” K. C. Hultszch, J. A. Jernelius, A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3773(20020215)41:43.0.CO;2-V”>Angew. Chem., Int. Ed. 2002, 41, 589.
65. “Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Acyclic Aliphatic Enones,” H. Mizutani, S. J. Degrado, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 779.
64. “New Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3′-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands,” R. R. Schrock, J. Y. Jamieson, S. J. Dolman, S. A. Miller, P. J. Bonitatebus, A. H. Hoveyda Organometallics 2002, 21, 409.
63. “Evaluation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts for Asymmetric Olefin Metathesis Reactions that Contain 3,3′-Diphenyl- or 3,3′-Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of Unsubstituted Molybdacyclobutane Complexes,” W. C. P. Tsang, R. R. Schrock, A. H. Hoveyda Organometallics 2001, 20, 5658.
62. “Immobilization of Olefin Metathesis Catalysts on Monolithic Sol-Gel. Practical, Efficient and Easily Recyclable Catalysts for Organic and Combinatorial Synthesis,” J. S. Kingsbury, S. B. Garber, J. M. Giftos, B. L. Gray, M. M. Okamoto, R. A. Farrer, J. T. Fourkas, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20011119)40:223.0.CO;2-L”>Angew. Chem., Int. Ed. 2001, 40, 4251.
61. “Mechanism of Enantioselective Ti-Catalyzed Strecker Reaction: Peptide-Based Metal Complexes as Bifunctional Catalysts,” N. S. Josephson, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 11594.
60. “Three-Component Catalytic Asymmetric Synthesis of Aliphatic Amines,” J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper J. Am. Chem. Soc. 2001, 123, 10409.
59. “Molybdenum Imido Alkylidene Complexes Containing Biphen Ligands That Have Silyl Groups Attached through the 6 and 6′ Methyl Group Carbon Atoms,” K. C. Hultszch, P. J. Bonitatebus, J. Jernelius, R. R. Schrock, A. H. Hoveyda Organometallics 2001, 20, 4705.
58. “Zr-Catalyzed Electrophilic Carbomagnesation of Aryl Olefins. Mechanism-Based Control of Zr-Mg Ligand Exchange,” J. de Armas, A. H. Hoveyda Org. Lett. 2001, 3, 2097.
57. “Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes,” D. S. La, E. S. Sattely, J. G. Ford, R. R. Schrock, A. H. Hoveyda J. Am.Chem. Soc. 2001, 123, 7767.
56. “Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Cu-Catalyzed Allylic Substitutions,” C. A. Luchaco-Cullis, H. Mizutani, K. E. Murphy, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-T”>Angew. Chem., Int. Ed. 2001, 40, 1456.
55. “A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis,” S. L. Aeilts, D. R. Cefalo, P. J. Bonitatebus, Jr., J. H. Houser, A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-G”>Angew. Chem., Int. Ed. 2001, 40, 1452.
54. “Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers by Mo-Catalyzed Olefin Metathesis,” D. R. Cefalo, A. F. Kiely, M. Wuchrer. J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 3139.
53. “Cross-Metathesis Reaction. Generation of Highly Functionalized Olefins from Unsaturated Alcohols,” J. Cossy, S. BouzBouz, A. H. Hoveyda J. Organomet. Chem. 2001, 634, 216.
52. “Enantioselective Synthesis of Arylamines Through Zr-Catalyzed Addition of Dialkylzincs to Imines. Reaction Development by Screening of Parallel Libraries,” J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper J. Am. Chem. Soc. 2001, 123, 984.
51. “Modular Peptide-Based Phosphine Ligands in Asymmetric Catalysis: Efficient and Enantioselective Cu-Catalyzed Conjugate Additions to Five-, and Six- and Seven-Membered Cyclic Enones,” S. J. Degrado, H. Mizutani, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 755.
50. “Synthesis of Molybdenum Imido Alkylidene Complexes that Contain 3,3′-Dialkyl-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2,2′-diolates (Alkyl = t-Bu or Adamantyl). Catalysts for Enantioselective Olefin Metathesis Reactions,” J. B. Alexander, R. R. Schrock, W. M. Davis, W., K. C. Hultzsh, A. H. Hoveyda, J. H. Houser, Organometallics 2000, 19, 3700.
49. “Modular Mo-Based Catalysts for Efficient Asymmetric Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Ethers and Acetals,” G. S. Weatherhead, J. H. Houser, J. G. Ford, J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda Tetrahedron Lett. 2000, 41, 9553. (Special issue in celebration of the 80th birthday of Professor Harry H. Wasserman)
48. “Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts,” S. B. Garber, J. S. Kingsbury, B. L. Gray, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 8168.
47. “Zr-Catalyzed Olefin Alkylations and Allylic Substitution Reactions with Electrophiles,” J. de Armas, S. P. Kolis, A. Hoveyda J. Am. Chem. Soc. 2000, 122, 5977.
46.“Ti-Catalyzed Regio- and Enantioselective Synthesis of Unsaturated α-Amino Nitriles, Amides and Acids. Catalyst Identification through Screening of Parallel Libraries,” J. R. Porter, W. G. Wirschun, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 2657.
45. “Synthesis of Molybdenum Imido Alkylidene Complexes Containing N,N’-Disubstituted 2,2′-Bisamido-1,1′-binaphthyl Ligands,” J. Y. Jamieson, R. R. Schrock, W. M. Davis, P. J. Bonitatebus, S. S. Zhu, A. H. Hoveyda Organometallics 2000, 19, 925.
44. “Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,” G. S. Weatherhead, G. J. Ford, E. J. Alexanian, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 1828.
43. “Zr-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis,” J. A. Adams, J. G. Ford, P. J. Stamatos, A. H. Hoveyda J. Org. Chem 1999, 64, 9690.
42. “Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,” D. S. La, J. G. Ford, E. S. Sattely, P. J. Bonitatebus, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 11603.
41. “Chiral Mo-Binol Complexes: Activity, Synthesis, and Structure. Efficient Enantioselective Six-Membered Ring Synthesis through Catalytic Metathesis,” S. S. Zhu, D. R. Cefalo, D. S. La, J. Y. Jamieson, W. M. Davis, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1999, 121, 8251.
40. “Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids, ” C. A. Krueger, K. W. Kuntz, C. D. Dzierba, W. G. Wirschun, J. D. Gleason, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 4284.
39. “Stereoselective Chelate-Controlled Addition of Grignard Reagents to Unsaturated Medium-Ring Heterocycles,” J. A. Adams, N. M. Heron, A. M. Koss, A. H. Hoveyda J. Org. Chem. 1999, 64, 854.
38. “Diastereoselective Intramolecular Cycloaddition of Vinylsilanes and Silyl Nitronates. Effective Control of Remote Acyclic Asymmetry,” D. G. J. Young, E. Gomez-Bengoa, A. H. Hoveyda J. Org. Chem. 1999, 64, 692.
37. “A Recyclable Ru-Based Metathesis Catalyst,” J. S. Kingsbury, J. P. A. Harrity, P. J. Bonitatebus, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 791.
36. “Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing Metathesis,” D. S. La, J. B. Alexander, D. R. Cefalo, D. D. Graf, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1998, 120, 9720.
35. “Zr-Catalyzed Kinetic Resolution of Allylic Ethers and Mo-Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)-Nebivolol,” C. W. Johannes, M. S. Visser, G. S. Weatherhead, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 8340.
34. “Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen-Mo Complex,” J. B. Alexander, D. S. La, D. R. Cefalo, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1998, 120, 4041.
33. “Ni-Catalyzed Asymmetric Addition of Grignard Reagents to Unsaturated Cyclic Acetals. The Influence of Added Phosphine on Enantioselectivity,” E. Gomez-Bengoa, N. M. Heron, M. T. Didiuk, C. A. Luchaco, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 7649.
32. “Chromenes through Metal-Catalyzed Reactions of Styrenyl Ethers. Mechanism and Utility in Synthesis,” J. P. A. Harrity, D. S. La, D. R. Cefalo, M. S. Visser, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 2343.
31. “Phosphine-Directed Stereo- & Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers,” M. T. Didiuk, J. P. Morken, A. H. Hoveyda Tetrahedron 1998, 54, 1117.
30. “Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1),” Z. Xu, C. W. Johannes, A. F. Houri, D. S. La, D. A. Cogan, G. E. Hofilena, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 10302.
29. “Stereoselective Heteroatom-Assisted Allylic Alkylation of Cyclic Ethers With Grignard Reagents. A Convenient Route to Enantiomerically Pure Carbocycles,” N. M. Heron, J. A. Adams, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 6205.
28. “Search for Chiral Catalysts Through Ligand Diversity: Substrate-Specific Catalysts and Ligand Screening on Solid Support,” K. D. Shimizu, B. M. Cole, C. A. Krueger, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 1997, 36, 1704.
27. “Synthesis of Amino Sugars Through a Highly Diastereoselective Dipolar Cycloaddition. Enantioselective Synthesis of the Carbohydrate Segment of Sch 38516,” Z. Xu, C. W. Johannes, D. S. La, G. E. Hofilena, A. H. Hoveyda Tetrahedron 1997, 53, 16377.
26. “Ru-Catalyzed Rearrangement of Styrenyl Ethers. Enantioselective Synthesis of Chromenes Through Zr- and Ru-Catalyzed Processes,” J. P. A. Harrity, M. S. Visser, J. D. Gleason, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 1488.
25. “Enantioselective Total Synthesis of Antifungal Agent Sch 38516,” Z. Xu, C. W. Johannes, S. S. Salman, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 10926.
24. “Discovery of Chiral Catalysts through Ligand Diversity: Ti-Catalyzed Enantioselective Addition of TMSCN to meso Epoxides,” B. M. Cole, K. D. Shimizu, C. A. Kruger, J. P. A. Harrity, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 1996, 35, 1668.
23. “Directed Regioselective Ni-Catalyzed Alkylation and Hydride Addition of Allylic Ethers. A Remarkable Turnover in Regioselectivity,” J. P. Morken, M. T. Didiuk, A. H. Hoveyda Tetrahedron Lett. 1996, 37, 3613.
22. “Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems,” M. S. Visser, J. P. A. Harrity, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 3779.
21. “Catalytic and Enantioselective Route to Medium-Ring Heterocycles. Asymmetric Zirconium-Catalyzed Ethylmagnesation of Seven- and Eight-Membered Rings,” M. S. Visser, N. M. Heron, M. T. Didiuk, J. F. Sagal, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 4291.
20. “Highly Diastereoselective Hydrosilation Reactions. Spirocyclic Siloxanes: Sources of Si-Based Lewis Acids,” D. G. J. Young, M. R. Hale, A. H. Hoveyda Tetrahedron Lett. 1996, 37, 827.
19. “Directed Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers,” M. T. Didiuk, J. P. Morken, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 7273.
18. “Cascade Catalysis in Synthesis. An Enantioselective Route to Sch 38516 (and Fluvirucin B1) Aglycon Macrolactam,” A. F. Houri, Z. Xu, D. A. Cogan, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 2943.
17. “Enantio-, Diastereo-, and Regioselective Zirconium-Catalyzed Carbomagnesation of Cyclic Ethers with Higher Alkyls of Magnesium. Utility in Synthesis and Mechanistic Implications,” M. T. Didiuk, C. W. Johannes, J. P. Morken, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 7097.
16. “Zirconocene-Catalyzed Kinetic Resolution of Dihydrofurans,” M. S. Visser, A. H. Hoveyda Tetrahedron 1995, 51, 4383.
15. “Diastereoselective Heteroatom-Directed Conjugate Addition of Silylcuprate Reagents to Unsaturated Carbonyls. A Stereoselective Route to β-Carbonyl Siloxanes,” M. R. Hale, A. H. Hoveyda J. Org. Chem. 1994, 59, 4370.
14. “Zirconium-Catalyzed Kinetic Resolution of Pyrans,” J. P. Morken, M. T. Didiuk, M. S. Visser, A. H. Hoveyda J. Am. Chem. Soc. 1994, 116, 3123.
13. “Zirconium-Catalyzed Asymmetric Carbomagnesation,” J. P. Morken, M. T. Didiuk, A. H. Hoveyda J. Am. Chem. Soc. 1993, 115, 6997.
12. “Regio- and Stereoselective Carbon-Carbon Bond Formation through Transition Metal Catalysis. The Influence of Catalyst Chirality on Selective Ethylmagnesation of Chiral, Nonracemic Alcohols and Ethers,” A. H. Hoveyda, J. P. Morken J. Org. Chem. 1993, 58, 4237.
11. “Zirconium-Catalyzed Ethylmagnesation of Hydroxylated Terminal Alkenes; A Catalytic and Diastereoselective Carbon-Carbon Bond-Forming Reaction,” A. F. Houri, M. T. Didiuk, Z. Xu, N. R. Horan, A. H. Hoveyda J. Am. Chem. Soc. 1993, 115, 6614.
10. “On the Mechanism of the Zirconium-Catalyzed Carbomagnesation Reaction. Efficient and Selective Catalytic Carbomagnesation with Higher Alkyls of Magnesium,” A. H. Hoveyda, J. P. Morken, A. F. Houri, Z. Xu J. Am. Chem. Soc. 1992, 114, 6692.
9. “Rhodium (I)- and Iridium (I)-Catalyzed Hydroboration Reactions: Scope and Synthetic Applications,” D. A. Evans, G. C. Fu, A. H. Hoveyda J. Am. Chem. Soc. 1992, 114, 6671.
8. “Siloxanes: Versatile Templates for Acyclic Stereocontrol. Synthesis of the C27-C33 Segment of Rapamycin,” M. R. Hale, A. H. Hoveyda J. Org. Chem. 1992, 57, 1643.
7. “Stereoselective Zirconium-Catalyzed Ethylmagnesation of Homoallylic Alcohols and Ethers. The Influence of Internal Lewis Bases on Substrate Reactivity,” A. H. Hoveyda, Z. Xu, J. P. Morken, A. F. Houri J. Am. Chem. Soc. 1991, 113, 8950.
6. “Stereoselective Formation of Carbon-Carbon Bonds Through Metal Catalysis. The Zirconium-Catalyzed Ethylmagnesation Reaction,” A. H. Hoveyda, Z. Xu J. Am. Chem. Soc. 1991, 113, 5079.
5. “Samarium-Catalyzed Intramolecular Tishchenko Reduction of β-Hydroxy Ketones. A Stereoselective Approach to the Synthesis of Differentiated Anti 1,3-Diol Monoesters,” D. A. Evans, A. H. Hoveyda J. Am. Chem. Soc. 1990, 112, 6447.
4. “Reduction of β-Hydroxy Ketones with Catecholborane. A Stereoselective Approach to the Synthesis of Syn-1,3-Diols,” D. A. Evans, A. H. Hoveyda J. Org. Chem. 1990, 55, 5190.
3. “The Rhodium(I)-Catalyzed Hydroboration of Olefins. The Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems,” D. A. Evans, G. C. Fu, A. H. Hoveyda J. Am. Chem. Soc. 1988, 110, 6917.
2. “Synthetic Studies of the Furan-Carbonyl Photocycloaddition Reaction. A Total Synthesis of (±)-Avenaciolide,” S. L. Schreiber, A. H. Hoveyda J. Am. Chem. Soc. 1984, 106, 7200.
1. “A Photochemical Route to the Formation of Threo Aldols,” S. L. Schreiber, A. H. Hoveyda, H-J. Wu J. Am. Chem. Soc. 1983, 105, 660.
REVIEWS, PERSPECTIVES, CONCEPT ARTICLES
43. “Taking Olefin Metathesis to the Limit: Stereocontrolled Synthesis of Trisubstituted Alkenes,” A. H. Hoveyda, C. Qin, X. Z. Sui, Q. Liu, X. Li, A. Nikbakht Acc. Chem. Res. 2023, 56, 2426.
42. “Catalytic and Stereoselective Transformations with Easily Accessible and Purchasable Allyl and Alkenyl Fluorides,” P. H. S. Paioti, S. A. Gonsales, S. Xu, A. Nikbakht, D. C. Fager, Q. Liu, A. H. Hoveyda Angew. Chem. Int. Ed. 2022, e202208742.
41. “Impact of Ethylene on Efficiency and Stereocontrol in Olefin Metathesis: When to Add It, When to Remove It,and When to Avoid It,” A. H. Hoveyda, Z. Liu, C. Qin, T. Koengeter, Y. Mu Angew. Chem. Int. Ed. 2020, 59, 22324.
40. “Sulfonate N-Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective C–C, C–B, C–H, and C–Si Bond Formation,” A. H. Hoveyda, Y. Zhou, Y. Shi, K. Brown, H. Wu, S. Torker Angew. Chem. Int. Ed. 2020, 59, 21304.
39. “Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes,” A. H. Hoveyda, M. J. Koh, K. Lee, J. Lee, in Organic Syntheses, S. E. Denmark, D. Hall, Eds; 2020, Vol 100, 959.
38. “Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems,” F. Romiti, J. del Pozo, P. H. S. Paioti, S. A. Gonsales, X. Li, F. W. W. Hartrampf, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 17952.
37. “Organoaluminum Compounds in Catalytic Enantioselective C–C Bond Forming Reactions,” K. P. McGrath, A. H. Hoveyda in The Chemistry of Organoaluminum Compounds., Z. Rappoport, I. Marek, Eds.; Wiley, Hoboken, 2017.
36. “Activation of B–B and B–Si Bonds and Synthesis of Organoboron and Organosilicon Compounds through Lewis Base Catalyzed Transformations,” A. Hoveyda, H. Wu, S. Radomkit, J. M. Garcia, F. Haeffner, K-S. Lee in Lewis Base Catalysis; E. Vedejs, S. E. Denmark. Eds.; VCH-Wiley, Weinheim, 2016, Vol 3, 967.
35. “Catalyst-Controlled Stereoselective Olefin Metathesis,” A. H. Hoveyda, R. K. M. Khan, S. Torker, S. J. Malcolmson, Handbook of Metathesis (Second Edition), R. H. Grubbs, D. J. O’Leary, Eds.; VCH-Wiley, Weinheim, 2015, Vol 2, 503.
34. “Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity,” A. H. Hoveyda J. Org. Chem. 2014, 79, 4763.
33. “Dichloro[[2-(1-methylethoxy-O)phenyl]- methylene](tricyclohexylphosphine) Ruthenium,” S. B. Garber, A. H. Hoveyda, R. K. M. Khan, T. J. Mann, e-EROS Encyclopedia of Reagents for Organic Synthesis
32. “Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin Angew. Chem. Int. Ed. 2010, 49, 34.
31. “Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in Metathesis in Natural Product Synthesis; Cossy, J. Ed.; Wiley-VCH, 2010, 343, (Chapter 12).
30. “Catalytic Enantioselective Olefin Metathesis,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in Catalytic Asymmetric Synthesis; Ojima, I. Ed.; Wiley-VCH, 2010, 739 (Chapter 8E).
29. “Molybdenum,[(S)-3,3′-bis(1,1-dimethylethyl)-5,5′,6,6′-tetramethyl[1,1′-biphenyl]-2,2′-diolato(2-)-kO,kO’]-2-methyl-2-phenylpropylidene)[tricyclo[3.3.1.13,7]decan-1-aminato(2-)],” S. J. Malcolmson, A. H. Hoveyda, R. R. Schrock, (Encyclopedia of Reagents for Organic Synthesis, Second Edition; Paquette, Crich, Fuchs, Molander, Eds.; 1765-1768); Wiley-VCH: Weinheim, 2009.
28. “The Remarkable Metal-catalysed Olefin Metathesis Reaction,” A. H. Hoveyda, A. R. Zhugralin Nature 2007, 450, 243.
27. “Small Peptides as Ligands for Catalytic Asymmetric Alkylations of Olefins. Rational Design of Catalysts or of Searches that Lead to Them?,” A. H. Hoveyda, A. W. Hird, M. A. Kacprzynski Chem. Commun. 2004, 16, 1779.
26. “Ru Complexes Bearing Bidentate Carbenes: From Innocent Curiosity to Uniquely Effective Catalysts for Olefin Metathesis,” A. H. Hoveyda, D. G. Gillingham, J. J. Van Veldhuizen, O. Kataoka, S. B. Garber, J. S. Kingsbury, J. P. A. Harrity Org. Biomol. Chem. 2004, 2, 8.
25. “Combinatorial Approaches,” A. H. Hoveyda, K. E. Murphy in Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 2004, 171 (Supplement to Chapter 39).
24. “Metathesis Reactions,” A. H. Hoveyda, R. R. Schrock in Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 2004, 207 (Chapter 44).
23. “Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin-Metathesis Catalysts,” R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2003, 42, 4592.
22. “Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda, R. R. Schrock in Handbook of Metathesis, R. H. Grubbs, Ed.; VCH-Wiley, Weinhein, 2003, 128 (Vol. 2).
21. “Polymer-Supported Olefin Metathesis Catalysts for Organic and Combinatorial Synthesis,” J. S. Kingsbury and A. H. Hoveyda in Polymeric Materials in Organic Synthesis and Catalysis, M. R. Buchmeiser, Ed.; VCH-Wiley, Weinheim, 2003, 467.
20. “Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda in Organic Synthesis Highlights V, H-G. Schmalz and T. Wirth, Eds; VCH-Wiley, Weinheim, 2003, 210.
19. “Chiral Zirconium Catalysts for Enantioselective Synthesis” A. H. Hoveyda in The Chemistry of Titanium and Zirconium Complexes, I. Marek, Ed.; VCH-Wiley, New York, 2002, 180.
18. “Diversity-Based Approaches to Chiral Catalyst Discovery,” A. H. Hoveyda in The Handbook of Combinatorial Chemistry, K. C. Nicolaou, R. Hanko, W. Hartwig, Eds.; VCH-Wiley, Weinheim, 2002, 991.
17. “Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3765(20010302)7:53.0.CO;2-3″>Chem. Eur. J. 2001, 7, 945.
16. “High-Throughput Screening of Titanium-Tripeptide Schiff Base Complexes for Catalytic Asymmetric Addition of Trimethylsilylcyanide to Epoxides and Imines,” K. W. Kuntz, M. L. Snapper, A. H. Hoveyda in High-Throughput Synthesis, Sucholeiki, I., Ed.; Marcel Dekker: New York, 2000, 283.
15. “Combinatorial Approaches to Chiral Catalyst Discovery,” M. L. Snapper and A. H. Hoveyda in Combinatorial Chemistry, Fenniri, H. Ed.; Oxford, 2000, 433.
14. “Asymmetric Catalysis in Target-Oriented Synthesis,” A. H. Hoveyda in Stimulating Concepts in Chemistry, Stoddart, F. J., Shibasaki, M., Vogtle, F., Eds; VCH: Weinheim, 2000, 145.
13. “Stereoselective Addition of Grignard Reagents to Alkenes,” A. H. Hoveyda, N. M. Heron, J. A. Adams in Grignard Reagents: New Developments, Richey, H. G., Ed.; John Wiley and Sons: New York, 2000, 107.
12. “Combinatorial Catalysis: Identification of Potent Chiral Catalysts Through Fluorescent Bead Signaling,” A. H. Hoveyda Chem. & Biol. 1999, 6, R305.
11. “Carbometallation of Carbon-Carbon Double Bonds,” A. H. Hoveyda, N. M. Heron in Comprehensive Asmmetric Catalysis, Vol. III, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer-Verlag, 1999, 431.
10. “Combinatorial Approaches,” K. D. Shimizu, M. L. Snapper, A. H. Hoveyda in Comprehensive Asmmetric Catalysis, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 1999, 1389 (Chapter 39).
9. “Combinatorial Catalyst Discovery,” K. W. Kuntz, M. L. Snapper, A. H. Hoveyda Curr. Opinions in Chem. & Biol. 1999, 3, 313.
8. “Metal-Catalyzed Kinetic Resolution Processes,” A. H. Hoveyda, M. T. Didiuk Curr. Org. Chem. 1998, 2, 489.
7. “High-Throughput Strategies for the Discovery of Catalysts,” K. D. Shimizu, M. L. Snapper, A. H. Hoveyda <a href="https://doi.org/10.1002/(SICI)1521-3765(19981002)4:103.0.CO;2-D”>Chem., Eur. J. 1998, 4, 1885.
6. “Catalyst Discovery Through Combinatorial Chemistry,” A. H. Hoveyda Chemistry & Biology 1998, 5, R187.
5. “Catalytic Ring-Closing Metathesis and the Development of Enantioselective Processes,” A. H. Hoveyda in Metathesis, Furstner, A., Ed.; Springer: Berlin, 1998, 105.
4. “Chiral Titanocenes and Zirconocenes in Synthesis,” A. H. Hoveyda and J. P. Morken in Metallocenes, Togni, A.; Halterman R., Eds.; VCH: Weinheim; 1998, Vol. 2, 625.
3. “Catalytic Enantioselective Addition of Grignard Reagents to Olefins,” A. H. Hoveyda in Transition Metals for Fine Chemicals and Organic Synthesis, Bolm, C. Ed.; VCH: Weinheim, 1998, 195.
2. “Enantioselective C-C and C-H Bond Formation Mediated or Catalyzed by Chiral ebthi Complexes of Titanium and Zirconium,” A. H. Hoveyda, J. P. Morken Angew. Chem. Int. Ed. 1996, 35, 1263.
1. “Substrate-Directable Chemical Reactions,” A. H. Hoveyda, D. A. Evans, G. C. Fu Chem. Rev. 1993, 93, 1307.
“Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes” F. Zhai, R. R. Schrock, A. H. Hoveyda, P. Müller Organometallics 2020, 39, 2486. 265.
“Sulfonate N‐Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C−C, C−B, C−H, and C−Si Bonds” A. H. Hoveyda, Y. Zhou, Y. Shi, M. K. Brown, H. Wu, S. Torker Angew. Chem. Int. Ed. 2020, 59, 21304. 264.
“Regio‐ and Enantioselective Synthesis of Trifluoromethyl‐Substituted Homoallylic α‐Tertiary NH2‐Amines by Reactions Facilitated by a Threonine‐Based Boron‐Containing Catalyst” D. C. Fager, R. J. Morrison, A. H. Hoveyda Angew. Chem. Int. Ed. 2020, 59, 11448. 263.
“A Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing Z-Alkenyl Chloride or Trifluoromethyl Group. A Protecting Group-Free Synthesis of Mycothiazole” R. J. Morrison, F. W. van der Mei, F. Romiti, A. H. Hoveyda J. Am. Chem. Soc. 2020, 142, 436. 262.
“Catalytic Enantioselective Conjugate Addition of Stereodefined Di- and Trisubstituted Alkenylaluminum Compounds to Acyclic Enones” K. P. McGrath, A. K. Hubbell, Y. Zhou, D. P.Santos, S. Torker, F. Romiti, A. H. Hoveyda Adv. Synth. Catal. 2020, 362, 370. (Special issue dedicated to the sixtieth birthday of Professor Eric N. Jacobsen)
“Catalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu−F β‑Elimination” P. H. S. Paioti, J. del Pozo, M. S. Mikus, J. Lee, M. J. Koh, F. Romiti, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 19917.
“Catalytic Enantioselective Addition of an Allyl Group to Ketones Containing a Tri-, a Di-, or a Monohalomethyl Moiety. Stereochemical Control Based on Distinctive Electronic and Steric Attributes of C–Cl, C–Br, and C–F Bonds” D. C. Fager, K. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 16125.
“Copper–Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis” Y. Sun, Y. Zhou, Y. Shi, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141,12087.
“Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F-Substituted Stereogenic Quaternary Center” S. Akiyama, K. Kubota, M. S. Mikus, P. H. S. Paioti, F. Romiti, Q. Liu, Y. Zhou, A. H. Hoveyda, H. Ito Angew. Chem. Int. Ed. 2019, 58, 11998.
"Silica‐Supported Molybdenum‐Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis” M. Pucino, F. Zhai, C. P. Gordon, D. Mance, A. H. Hoveyda, R. R. Schrock, C. Copéret Angew. Chem. Int. Ed. 2019, 58, 11816.
“Ru-Based Catechothiolate Complexes Bearing an Unstaturated NHC Ligand: Effective Cross-Metathesis Catalysts for Synthesis of (Z)-α,β-Unsaturated Esters, Caboxylic Acids and Primary, Secondary, and Weinreb Amides” Z. Liu, C. Xu, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 7137.
“E– and Z-, Di- and Tri-Substituted Alkenyl Nitriles Through Catalytic Cross-Metathesis” Y. Mu, T. Nguyen, M.J. Koh, R. R. Schrock, A. H. Hoveyda Nat. Chem. 2019, 11, 478.
“Delayed Catalyst Function Enables Direct Enantioselective Conversion of Nitriles to NH2-Amines” S. Zhang, J. del Pozo, F. Romiti, Y. Mu, S. Torker, A. H. Hoveyda Science 2019, 364, 45.
“Traceless Protection for More Broadly Applicable Olefin Metathesis” Y. Mu, T. Nguyen, F. W. van der Mei, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2019, 58, 5365.
“Racemic Vinylallenes in Catalytic Enantioselective Mutlicomponent Processes. Rapid Generation of Complexity through 1,6-Conjugate Additions” Y. Huang, S. Torker, X. Li, J. del Pozo, A. H. Hoveyda Angew. Chem. Int. Ed. 2019, 58, 2685.
“SN2″-Selective and Enantioselective Substitution with Unsaturated Organoboron Compounds and Catalyzed by a Sulfonate-Containing NHC-Cu Complex” Y. Zhou, Y. Shi, S. Torker, and A. H. Hoveyda J. Am. Chem. Soc. 2018, 140, 16842.
“Syntheses of Molybendenum Oxo Benzylidene Complexes” F. Zhai, K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. Müller J. Am. Chem. Soc. 2018, 140, 13609.
“γ-, Diastereo-, and Enantioselective Addition of MEMO-Substituted Allylboron Compounds to Aldimines Catalyzed by Organoboron-Ammonium Complexes” R. J. Morrison, A. H. Hoveyda Angew. Chem. Int. Ed. 2018, 57, 11654.
“Syntheses of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN” S. VenkatRamani, R.R. Schrock, A. H. Hoveyda, P. Müller, C. Tsay Organometallics 2018, 37, 1641.
“Syntheses of Molybendenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex” K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. Müller J. Am. Chem. Soc. 2018, 140, 2797.
“Enantioselective Synthesis for Trisubstituted Allenyl—B(pin) Compounds by Phosphine—Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Intergrity of Cu—Allenyl Intermediates” Y. Huang, J. del Pozo, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2018, 140, 2643.
“Mechanism-based Enhancement of Scope and Enantioselectivity for Reactions Involving a Copper-Substituted Stereogenic Carbon Centre” J. Lee, S. Radomkit, S. Torker, J. del Pozo, A. H. Hoveyda Nat. Chem. 2018, 10, 99.
“Synthesis of E-and Z-Trisubstituted Alkenes by Catalytic Cross-Metathesis” T. T. Nguyen, M. J. Koh, T. J. Mann, R. R. Schrock, A. H. Hoveyda Nature 2017, 552, 347.
243. “Synthesis of Z– or E-Trisubstituted Allylic Alcohols and Ethers by Kinetically Controlled Cross-Metathesis with a Ru Catechothiolate Complex” C. Xu, Z. Liu, S. Torker, X. Shen, D. Xu, A.H. Hoveyda J. Am. Chem. Soc. 2017, 139, 15640.
242. “Synthesis of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCl and Diphenylmenthylphosphine” K. V. Bukhryakov, S. VenkatRamani, C. Tsay, A. Hoveyda, R. R. Schrock Organometallics 2017, 36, 4208.
241. “Enantioselective Total Synthesis of (—)-Deoxoapodine” T. Kang, K. L. White, T. J. Mann, A. H. Hoveyda, M. Movassaghi Angew. Chem. Int. Ed. 2017, 56, 13857.
240. “In Situ Methylene Capping: A General Strategy for Efficient Stereoretentive Catalytic Olefin Metathesis. The Concept, Methodological Implications, and Applications to Synthesis of Biologically Active Compounds” C. Xu, X. Shen, A. H. Hoveyda J. Am. Chem. Soc. 2017, 139, 10919.
239. “Catalytic Diastereo- and Enantioselective Additions of Versatile Allyl Groups to N-H Ketimines,“ H. Jang, F. Romiti, S. Torker, A. H. Hoveyda Nat. Chem. 2017, 9, 1269.
238. “Practical, Broadly Applicable, α- Selective, Z-Selective, Diastereoselective and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri- and Polyfluoroalkyl Ketones,“ F. W. van der Mei, C. Qin, R. J. Morrison, A. H. Hoveyda J. Am. Chem. Soc. 2017, 139, 9053.
237. “Practical, Efficient, and Broadly Applicable Synthesis of Readily Differentiable Vicinal Diboronate Compounds by Catalytic Three-Component Reactions,“ S. Radomkit, Z. Liu, A. Closs, M.S. Mikus, A. H. HoveydaTetrahedron, 2017, 73, 5011. (Special issue in honor of Professor Ben Feringa)
236. “Electronically Activated Organoboron Catalysts for Enantioselective Propargyl Addition to Trifluoromethyl Ketones,“ N.W. Mszar, M. S. Mikus, S. Torker, F. Haeffner, A. H. Hoveyda Angew. Chem. Int. Ed. 2017, 56, 8736.
235. “Synthesis of 2,6,-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X + I, Li, OH, SH, N3, or NH2,“ K.V. Bukhryakov, R. R. Schrock, A. H. Hoveyda, P. Müller, J. Becker Org. Lett. 2017, 19, 2607.
234. “Molybdenum Chloride Catalysts for Z-Selective Olefin Metathesis Reactions,“ M. J. Koh, T. T. Nguyen, J. K. Lam, S. Torker, J. Hyvl, R. R. Schrock, A. H. Hoveyda Nature 2017, 542, 80.
233. “Kinetically E-Selective Macrocyclic Ring-Closing Metathesis,“ X. Shen, T. T. Nguyen, M. J. Koh, D. Xu, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda Nature 2017, 541, 380.
232. “Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioslective Catalytic Sequence of Cu—H Addition to Vinyl-B(pin)/Allylic Substitution,” J. Lee, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2017, 56, 821.
231. “Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene,” J. Lam, C. Zhu, K. V. Bukhryakov, P. Müller, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 2016, 138, 15774.
230. “Pentacoordinate Ruthenium(ll) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation,” M. S. Mikus, S. Torker, C. Xu, B. Li, A. H. Hoveyda Organometallics 2016, 35, 3878.
229. “Synthesis of Linear (Z)- α , β -Unsaturated Esters by Catalytic Crosss-Metathesis. The Influence of Acetonitrile,” E. C. Yu, B. M. Johnson, E. M. Townsend, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 13210.
228. “Catalytic Enantioselective 1,6-Conjugate Additions of Propargyl and Allyl Groups,” F. Meng, X. Li, S. Torker, Y. Shi, X. Shen, A. H. Hoveyda Nature 2016, 537, 387.
227. “Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene,” X. Li, F. Meng, S. Torker, Y. Shi, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 9997.
226. “Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl–B(pin) Compounds to Ketones and α -Ketoesters,” D. W. Robbins, K. Lee, D. L. Silverio, A. Volkov, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 9610.
225. “Catalytic Enantioselective Addition of Organoboron Reagents to Fluoroketones Controlled by Electrostatic Interactions,” K. Lee, D. L. Silverio, S. Torker, F. Haeffner, D. W. Robbins, F. W. van der Mei, A. H. Hoveyda Nat. Chem. 2016, 8, 768.
224. “Kinetically controlled E-Selective Catalytic Olefin Metathesis,” T. T. Nguyen, M. J. Koh, X. Shen, F. Romiti, R. R. Schrock, A. H. Hoveyda Science 2016, 352, 569.
223. “Controllable ROMP Tacticity by Harnessing the Fluxionality of Stereogenic-at-Ruthenium Complexes,“ M. S. Mikus, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 4997.
222. “Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective γ-Additions of Allylboron Moieties to Aldimines,” F. W. van der Mei, H. Miyamoto, D. L. Silverio, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 4701.
221. “Catalytic SN2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis,” Y. Shi, A. H. Hoveyda Angew. Chem. Int. Ed. 2016, 55, 3455.
220. “Direct Synthesis of Z-Alkenyl Halides through Catalytic Cross-Methathesis,” M. J. Koh, T. T. Nguyen, H. Zhang, R. R. Schrock, A. H. Hoveyda Nature 2016, 531, 459.
219. “Regarding a Persisting Puzzle in Olefin Metathesis with Ru Complexes: Why are Transformations of Alkenes with a Small Substituent Z-Selective?,” S. Torker, M. J. Koh, R. K. Khan, A. H. Hoveyda Organometallics 2016, 35, 543.
218. “Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to β Unsaturated Carbonyl Compounds” H. Wu, J. M. Garcia, F. Haeffner, S. Radomkit, A. R. Zhugralin, A. H. Hoveyda J. Am. Chem. Soc. 2015, 137, 10585.
217. “N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes,” Y. Shi , B. Jung , S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2015, 137, 8948.
216. “N-Substituted Tertiary and O-Substituted Quaternary Carbon Stereogenic Centers by Site-, Diastereo- and Enantioselective Vinylogous Mannich Reactions,” D. L. Silverio, P. Fu, E. L. Carswell, M. L. Snapper, A. H. Hoveyda Tetrahedron Lett. 2015, 56, 3489. (Special issue in memory of Professor Harry H. Wasserman)
215. “Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand,” J. C. Axtell, R. R. Schrock, Peter Müller, A. H. Hoveyda Organometallics 2015, 34, 2110.
214. “Synthesis of Alternating trans-AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes,” H. Jeong, J. M. John, R. R. Schrock, A. H. HoveydaJ. Am. Chem. Soc. 2015, 137, 2239.
213. “High-Value Alcohols and Higher-Oxidation-State Compounds by Catalytic Z-Selective Cross-Metathesis,” M. J. Koh, R. K. M. Khan, S. Torker, M. Yu, M. S. Mikus, A. H. Hoveyda Nature 2015, 517, 181.
212. “Catalyst-Controlled Stereoselective Olefin Metathesis as a Principal Strategy in Multistep Synthesis Design: A Concise Route to (+)-Neopeltolide,” M. Yu, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2015, 54, 215.
211. “Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis,” H. Zhang, E. C. Yu, S. Torker, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 16493.
210. “Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1,” A. W. H. Speed, T. J. Mann, R. V. O’Brien, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 16136.
209. “Reactivity and Selectivity Differences between Catecholate and Catechothiolate Ru Complexes. Implications Regarding Design of Stereoselective Olefin Metathesis Catalysts,” R. K. M. Khan, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 14337.
208. “Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands,” E. M. Townsend, J. Hyvl, W. P. Forrest, R. R. Schrock, P. Müller, A. H. Hoveyda Organometallics 2014, 33, 5334.
207. “Multifunctional Organoboron Compounds for Scalable Natural Product Synthesis,” F. Meng, K. P. McGrath, A. H. Hoveyda Nature 2014, 513, 367.
206. “Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand,” J. C. Axtell, R. R. Schrock, P. Müller, S. J. Smith, A. H. Hoveyda Organometallics 2014, 33, 5342.
205. “Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity,” H. Jang, B. Jung, A. H. Hoveyda Org. Lett. 2014, 16, 4658.
204. “Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex,” F. Meng, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 11304.
203. “Synthesis of (±)-Tetrapetalone A-Me Aglycon,” P. N. Carlsen, T. J. Mann, A. H. Hoveyda, A. J. Frontier Angew. Chem. Int. Ed. 2014, 53, 9334.
202. “An Efficient, Practical, and Enantioselective Method for Synthesis of Homoallenylamides Catalyzed by an Aminoalcohol-Derived, Boron-Based Catalyst,” H. Wu, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3780.
201. “NHC–Cu-Catalyzed Addition of Propargylboron Reagents to Phosphinoylimines. Enantioselective Synthesis of Trimethylsilyl-Substituted Homoallenylamides and Application to the Synthesis of S-(–)-Cyclooroidin,” N. W. Mszar, F. Haeffner, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3362.
200. “The Influence of Anionic Ligands on Stereoisomerism of Ru Carbenes and Their Importance to Efficiency and Selectivity of Catalytic Olefin Metathesis Reactions,” S. Torker, R. K. M. Khan, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 3439.
199. “Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones,” S. Radomkit, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53, 3387.
198. “A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis,” F. Gao, J. L. Carr, A. H. Hoveyda J. Am. Chem. Soc. 2014, 136, 2149.
197. “Broadly Applicable Z– and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex,” M. J. Koh, R. K. M. Khan, S. Torker, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53, 1968.
196. “A Multicomponent Ni-, Zr-, and Cu-Catalyzed Strategy for Enantioselective Synthesis of Alkenyl-Substituted Quaternary Carbons,” K. P. McGrath, A. H. Hoveyda Angew. Chem. Int. Ed. 2014, 53,1910.
195. “High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes,” E. M. Townsend, S. M. Kilyanek, R. R. Schrock, P.Müller, S. J. Smith, A. H. Hoveyda Organometallics 2013, 32, 4612.
194. “Enantioselective Silyl Protection of Alcohols Promoted by a Combination of Chiral and Achiral Lewis Basic Catalysts,” N. Mannville, H. Alite, F. Haeffner, A. H. Hoveyda, M. L. Snapper Nat. Chem. 2013, 5, 768.
193. “Catalytic Z-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis,” T. J. Mann, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 8395.
192. “Readily Accessible and Easily Modifiable Ru-Based Catalysts for Efficient and Z-Selective Ring-Opening Metathesis Polymerization and Ring-Opening/Cross-Metathesis,” R. K. M. Khan, S. Torker, A. H. Hoveyda J. Am. Chem. Soc. 2013, 135, 10258.
191. “Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Cu-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones,” J. A. Dabrowski, M. T. Villaume, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 8156.
190. “Combining NHC–Cu and BØnsted Base Catalysis: Enantioselective Allylic Substitition/Conjugate Addition with Alkynyllithium Reagents and Stereospecific Isomerization of Products to Trisubstituted Allenes,” J. A. Dabrowski, J. Haeffner, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 7694.
189. “Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis,” E. T. Kiesewetter, R. V. O’Brien, E. C. Yu, S. J. Meek, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2013, 135, 6026.
188. “Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones,” F. Meng, H. Jang, B. Jung, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 5046.
187. “NHC-Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism,” F. Meng, B. Jung, F. Haeffner, A. H. Hoveyda Org. Lett. 2013, 15, 1414.
186. “Simple Organic Molecules as Catalysts for Enantioselective Synthesis of Amines and Alcohols,” D. Silverio, S. Torker, T. Pilyugina, E. M. Vieira, M. L. Snapper, F. Haeffner, A. H. Hoveyda Nature 2013, 494, 216.
185. “Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total syntheses of Epilachnene, Yuzu Lactone, Ambrettolide, Epothilone C, and Nakadomarin A,” C. Wang, M. Yu, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda Chem. Eur. J. 2013, 19, 2726.
184. “Exceptionally E– and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes,” F. Meng, H. Jang, A. H. Hoveyda Chem. Eur. J. 2013, 19, 3204.
183. “Molybdenum-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysis for Efficient Z-selective Synthesis of a Macrocylic Trisubstituted Alkene by Ring Closing Metathesis,” C. Wang, F. Haeffner, R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2013, 52, 1939.
182. “NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes,” K.-S. Lee, H. Wu, F. Haeffner, A. H. Hoveyda Organometallics 2012, 31, 7823.
181. “Z– and Enantioselective Ring-Opening/Cross-Metathesis with Enol Ethers Catalyzed by Stereogenic-at-Ru Carbenes: Reactivity, Selectivity, and Curtin-Hammett Kinetics,” R. K. M. Khan, R. V. O’Brien, S. Torker, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 12774.
180. “Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways,” R. K. M. Khan, A. R. Zhugralin, S. Torker, R. V. O’Brien, P. J. Lombardi, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 12438.
179. “Z-selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes,” E. M. Townsend, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 11334.
178. “Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes,” A. G. Lichtscheidl, V. W. L. Ng, P. Müller, M. K. Takase, R. R. Schrock, S. J. Malcolmson, S. J. Meek, B. Li, E. T. Kiesewetter, A. H. Hoveyda Organometallics 2012, 31, 4558.
177. “Cu-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents,” F. Gao, J. L. Carr, A. H. Hoveyda Angew. Chem. Int. Ed. 2012, 51, 6613.
176. “A Robust, Efficient and Highly Enantioselective Method for Synthesis of Homopropargyl Amines,” E. M. Vieira, F. Haeffner, M. L. Snapper, A. H. Hoveyda Angew. Chem. Int. Ed. 2012, 51, 6618.
175. “Metal-Free Catalytic Enantioselective C-B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes,” H. Wu, S. Radomkit, J. M. O’Brien, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 8277.
174. “Enol Ethers as Substrates for Efficient Z– and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes,” M. Yu, I. Ibrahem, M. Hasegawa, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 2788.
173. “Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution,” B. Jung, A. H. Hoveyda J. Am. Chem. Soc. 2012, 134, 1490.
172. “Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes,” D. V. Peryshkov, R. R. Schrock, M. K. Takase, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 20754.
171. “Synthesis of Macrocyclic Natural Products by Catalyst-Controlled Stereoselective Ring-Closing Metathesis,” M. Yu, C. Wang, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda Nature 2011, 479, 88.
170. “Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures,” S. C. Marinescu, D. S. Levine, Y. Zhao, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 11512.
169. “Regiodivergent Reactions through Catalytic Enantioselective Silylation of Chiral Diols. Synthesis of Sapinofuranone A,” J. M. Rodrigo, Y. Zhao, A. H. Hoveyda, M. L. Snapper Org. Lett. 2011, 13, 3778.
168. “NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes,” R. Corberan, N. W. Mszar, A. H. Hoveyda Angew. Chem. Int. Ed. 2011, 50, 7079.
167. “Metal-Free Catalytic C-Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls,” J. M. O’Brien, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 7712.
166. “Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC-Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity,” H. Jang, A. R. Zhugralin, Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 7859.
165. “Room-Temperature Z-Selective Homocoupling of α-Olefins by Tungsten Catalysts,” S. C. Marinescu, R. R. Schrock, P. Müller, M. K. Takase, A. H. Hoveyda Organometallics 2011, 30, 1780.
164. “Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents,” J. A. Dabrowski, F. Gao, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 4778.
163. “Catalytic Z-Selective Olefin Cross-Metathesis for Natural Product Synthesis,” S. J. Meek, R. V. O’Brien, J. Llaveria, R. R. Schrock, A. H. Hoveyda Nature 2011, 471, 461.
162. “Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl- or Alkene-Substituted Aldimines Catalyzed by Chiral C-Symmetric NHC-Cu-Complexes,” E. M. Vieira, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 3332.
161. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes,” Y. Zhao, A. H. Hoveyda, R. R. Schrock Org. Lett. 2011, 13, 784.
160. “Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones,” T. L. May, J. A. Dabrowski, A. H. Hoveyda J. Am. Chem. Soc. 2011, 133, 736.
159. “Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinyaluminum Reagents,” F. Gao, K. P. McGrath, Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 14315.
158. “Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Hetero-aryllithium Reagents and Aluminum Chlorides,” F. Gao, Y. Lee, K. Mandai, A. H. Hoveyda Angew. Chem., Int. Ed. 2010, 49, 8370.
157. “α -Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes. Practical Syntheses of Internal Vinyl Aluminums, Halides or Boronates,” F. Gao, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 10961.
155. “Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions,” A. Guzman-Martinez, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 10634.
154. “Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes,” K.-S. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2010, 132, 2898.
153. “Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Cu-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E alkenes,” K. Akiyama, F. Gao, A. H. Hoveyda Angew. Chem., Int. Ed. 2010, 49, 419.
152. “Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC-Cu-Catalyzed Boron-Copper Additions to Terminal Alkynes,” Y. Lee, H. Jang, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 18234.
151. “Highly Z-Selective Metathesis Homocoupling of Terminal Olefins,” A. J. Jiang, Y. Zhao, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 16630.
150. “The Significance of Degenerate Processes to Enantioselective Olefin Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes,” S. J. Meek, S. J. Malcolmson, B. Li, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 16407.
149. “Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,” S. C. Marinescu, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 10840.
148. “Stereogenic-at-Metal Zn- and Al-based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations,” Y. Lee, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 11625.
147. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-Mo Monoalkoxide and Monoaryloxide Complexes. Efficient Synthesis of Cyclic Dienes Not Accessible through Reactions with Ru Carbenes,” Y.-J. Lee, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 10652.
146. “H-Bonding as an Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis,” A. H. Hoveyda, P. J. Lombardi, R. V. O’Brien, A. R. Zhugralin J. Am. Chem. Soc. 2009, 131, 8378.
145. “Z-Selective Olefin Metathesis Processes Catalyzed by a Molybdenum Hexaisopropylterphenoxide Monopyrrolide Complex,” M. M. Flook, A. J. Jiang, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 7962.
144. “Monodentate Non-C2-Symmetric Chiral N-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones,” K.-S. Lee, A. H. Hoveyda J. Org. Chem. 2009, 74, 4455.
143. “Efficient C-B Bond Formation Promoted by N-Heterocyclic Carbenes. Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls,” K.-S. Lee, A. R. Zhugralin, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 7253.
142. “Efficient Boron-Copper Additions to Aryl-Substituted Alkenes Promoted by NHC-Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions,” Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 3160.
141. “Highly Z– and Enantioselective Ring-Opening/Cross Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes,” I. Ibrahem, M. Yu, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 3844.
140. “Design and Stereoselective Preparation of a New Class of Chiral Olefin Metathesis Catalysts and Application to Enantioselective Synthesis of Quebrachamine. Catalyst Development Inspired by Natural Product Synthesis,” E. S. Sattely, S. J. Meek, S. J. Malcolmson, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 943.
139. “Inversion of Configuration at the Metal in Diastereomeric Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,” S. C. Marinescu, R. R. Schrock, B. Li, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 58.
138. “Enantioselective Synthesis of P-Stereogenic Phosphinates and Phosphine Oxides by Mo-Catalyzed Asymmetric Ring-Closing Metathesis,” J. S. Harvey, S. J. Malcolmson, K. S. Dunne, S. J. Meek, A. L. Thompson, R. R. Schrock, A. H. Hoveyda, V. Gouverneur Angew. Chem., Int. Ed. 2009, 48, 762.
137. “Catalytic Enantioselective Silylation of Acyclic and Cyclic Triols and Application to Total Syntheses of Cleroindicins D, F, and C,” Z. You, A. H. Hoveyda, M. L. Snapper Angew. Chem., Int. Ed. 2009, 48, 547.
136. “Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism,” L. C. Wieland, E. M. Vieira, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2009, 131, 570.
135. “Three-Component Ag-Catalyzed Enantioselective Vinylogous Mannich and Aza-Diels-Alder Reactions with Alkyl-Substituted Aldehydes,” H. Mandai, K. Mandai, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 17961.
134. “Highly Efficient Molybdenum-Based Catalysts for Enantioselective Alkene Metathesis,” S. J. Malcolmson, S. J. Meek, E. S. Sattely, R. R, Schrock, A. H. Hoveyda Nature 2008, 456, 933.
133. “Enantioselective Total Synthesis of Clavirolide C. Applications of Cu-Catalyzed Asymmetric Conjugate Additions and Ru-Catalyzed Ring-Closing Methathesis,” M. K. Brown, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 12904.
132. “Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones,” T. L. May, M. K. Brown, A. H. Hoveyda Angew. Chem., Int. Ed. 2008, 47, 7358.
131. “Aluminum-Catalyzed Asymmetric Alkylations of Pyridyl-Substituted Alkynyl Ketones with Dialkylzinc Reagents,” D. K. Friel, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 9942.
130. “Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis of N-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl- and Trifluoroalkyl-Substituted Ketoimines,” P. Fu, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 5530.
129. “Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents,” Y. Lee, K. Akiyama, D. Gillingham, M. K. Brown, A. H. Hoveyda J. Am. Chem. Soc. 2008, 130, 446.
128. “Kinetic Resolution of 1,2-Diols through Highly Site- and Enantioselective Catalytic Silylation,” Y. Zhao, A. W. Mitra, A. H. Hoveyda, M. L. Snapper Angew. Chem., Int. Ed. 2007, 46, 8471.
127. “Synthesis of Monoalkoxide Monopyrrolyl Complexes of the Type Mo(NR)(CHR’)(OR”)(pyrrolyl). Enyne Metathesis with High Oxidation State Catalysts,” R. Singh, R. R. Schrock, P. Müller, A. H. Hoveyda J. Am. Chem. Soc. 2007, 129, 12654.
126. “Cu-Catalyzed Asymmetric Conjugate Additions of Dialkyl- and Diarylzinc Reagents to Acyclic β-Silyl-α , β-Unsaturated Ketones. Synthesis of Allylsilanes in High Diastereo- and Enantiomeric Purity,” M. A. Kacprzynski, S. A. Kazane, T. L. May, A. H. Hoveyda Org. Lett. 2007, 9, 3187.
125. “Comparison of Ru- and Mo- Based Chiral Olefin Metathesis Catalysts. Complementarity in Asymmetric Ring-Opening/Cross-Metathesis Reactions of Oxa- and Azabicycles,” G. A. Cortez, C. A. Baxter, R. R. Schrock, A. H. Hoveyda Org. Lett. 2007, 9, 2871.
124. “Molybdenum Imido Alkylidene Metathesis Catalysts That Contain Electron-Withdrawing Biphenolates or Binaphtholates,” R. Singh, C. Czekelius, R. R. Schrock, P. M. Müller, A. H. Hoveyda Organometallics 2007, 26, 2528.
122. “Efficient Enantioselective Synthesis of Piperidines through Catalytic Asymmetric Ring-Opening/Cross Metathesis Reactions,” G. A. Cortez, R. R. Schrock, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 4534.
121. “Directed Catalytic Asymmetric Olefin Metathesis. Selectivity Control by Enoate and Ynoate Groups in Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis,” R. E. Guidici, A. H. Hoveyda J. Am. Chem. Soc. 2007, 129, 3824.
120. “Chiral N-Heterocyclic Carbenes in Natural Product Synthesis. Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C,” D. G. Gillingham, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 3860.
119. “New Enantiomerically Pure Alkyimido Molybdenum-Based Alkylidene Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts,” T. S. Pilyugina, R. R. Schrock, P. Müller, A. H. Hoveyda Organometallics 2007, 26, 831.
118. “All-Carbon Quaternary Stereogenic Centers by Enantioselective Cu-Catalyzed Conjugate Additions Promoted by a Chiral N-Heterocyclic Carbene,” M. K. Brown, T. L. May, C. A. Baxter, A. H. Hoveyda Angew. Chem., Int. Ed. 2007, 46, 1097.
117. “Dipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,” A. S. Hock, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 16373.
116. “Lewis Base Activation of Grignard Reagents with N-Heterocyclic Carbenes. Cu-Free Catalytic Enantioselective Additions to γ-Chloro α -,β-Unsaturated Esters,” Y. Lee, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 15604.
115. “A Highly Efficient and Practical Method for Catalytic Asymmetric Vinylogous Mannich (AVM) Reactions,” E. L. Carswell, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 2006, 45, 7230.
114. “Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,” A. Sinha, R. R. Schrock, P. Muller, A. H. Hoveyda Organometallics 2006, 25, 4621.
113. “Enantioselective Silyl Protection of Alcohols Catalysed by an Amino Acid-Based Small-Molecule,” Y. Zhao, J. Rodrigo, A. H. Hoveyda, M. L. Snapper Nature 2006, 443, 67.
112. “A Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to β-Substituted Cyclic Enones,” K.-S. Lee, M. K. Brown, A. W. Hird, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 7182.
111. “A Chiral Ag-based Catalyst for Practical, Efficient and Highly Enantioselective Additions of Enolsilanes to α-Ketoesters,” L. C. Akullian, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 6532.
110. “Operationally Simple, Efficient, and Diastereoselective Synthesis of cis-2,6-Disubstituted-4-Methylene Tetrahydropyrans Catalyzed by Triflic Acid,” A. Puglisi, A.-L. Lee, R. R. Schrock, A. H. Hoveyda Org. Lett. 2006, 8, 1871.
109. “Enantioselective Synthesis of Cyclic Enol Ethers and All-Carbon Quaternary Stereogenic Centers through Catalytic Asymmetric Ring-Closing Metathesis,” A.-L. Lee, S. J. Malcolmson, A. Puglisi, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2006, 128, 5153.
108. “Al-Catalyzed Enantioselective Alkylation of α-Ketoesters by Dialkylzinc Reagents. Enhancement of Enantioselectivity and Reactivity by an Achiral Lewis Base Additive,” L. C. Wieland, H. Deng, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 15453.
107. “Catalytic Enantioselective Alkylations of Tetrasubstituted Olefins. Synthesis of All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Enones,” A. W. Hird, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 14988.
106. “Highly Enantioselective Cu-Catalyzed Conjugate Additions of Dialkylzinc Reagents to Unsaturated Furanones and Pyranones: Preparation of Air Stable and Catalytically Active Cu.Peptide Complexes,” M. K. Brown, S. J. Degrado, A. H. Hoveyda Angew. Chem., Int. Ed. 2005, 44, 5306.
105. “Proline-Based N-Oxides as Readily Available and Modular Chiral Catalysts. Enantioselective Reactions of Allyltrichlorosilane with Aldehydes,” J. F. Traverse, Y. Zhao, A. H. Hoveyda, M. L. Snapper Org. Lett. 2005, 7, 3151.
104. “Practical and Highly Enantioselective Synthesis of β-Alkynyl-β-amino Esters through Ag-Catalyzed Asymmetric Mannich Reactions of Silylketene Acetals and Alkynyl Imines,” N. S. Josephsohn, E. L. Carswell, M. L. Snapper, A. H. Hoveyda Org. Lett. 2005, 7, 2711.
103. “Enantioselective Synthesis of Cyclic Amides and Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis,” E. S. Sattely, G. A. Cortez, D. C. Moebius, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 8526.
102. “Isocomplestatin: Total Synthesis and Stereochemical Revision,” T. Shinohara, H. Deng, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 7334.
101. “A Readily Available Chiral Ag-Based N-Heterocyclic Carbene Complex for Use in Efficient and Highly Enantioselective Ru-Catalyzed Olefin Metathesis and Cu-Catalyzed Allylic Alkylation Reactions,” J. J. Van Veldhuizen, J. E. Campbell, R. E. Guidici, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 6877.
100. “Enantioselective Synthesis of Nitroalkanes Bearing All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions,” J. Wu, D. M. Mampreian, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 4584.
99. “Catalytic Enantioselective Synthesis of Quaternary All-Carbon Stereogenic Centers. Preparation of α,α’-Disubstituted-β,γ-Unsaturated Esters through Cu-Catalyzed Asymmetric Allylic Alkylations,” K. E. Murphy, A. H. Hoveyda Org Lett. 2005, 7, 1255.
98. “Asymmetric Synthesis of Acyclic Amines Through Zr- and Hf-Catalyzed Enantioselective Addition of Alkylzinc Reagents to Imines,” L. C. Akullian, J. R. Porter, J. F. Traverse, M. L. Snapper, A. H. Hoveyda Adv. Synth. Catal. 2005, 347, 417.
97. “Regarding the Mechanism of Olefin Metathesis with Sol-Gel-Supported Ru-Based Complexes Bearing a Bidentate Carbene Ligand. Spectroscopic Evidence for Return of the Propagating Ru Carbene,” J. S. Kingsbury, A. H. Hoveyda J. Am. Chem. Soc. 2005, 127, 4510.
96. “Efficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru-Catalyzed Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM),” D. G. Gillingham, O. Kataoka, S. B. Garber, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 12288.
95. “Bidentate NHC-Based Chiral Ligands for Efficient Cu-Catalyzed Enantioselective Allylic Alkylations: Structure and Activity of an Air-Stable Chiral Cu Complex,” A. O. Larsen, W. Leu, C. N. Oberhuber, J. E. Campbell, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 11130.
94. “Efficient Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Aromatic and Aliphatic Acyclic Nitroalkenes,” D. M. Mampreian, A. H. Hoveyda Org. Lett., 2004, 6, 2829.
93. “Investigations of Reactions between Chiral Molybdenum Imido Alkylidene Complexes and Ethylene: Observation of Unsolvated Base-Free Methylene Complexes, Metalacyclobutane and Metalacyclopentane Complexes, and Molybdenum(IV) Olefin Complexes,” W. C. P. Tsang, J. Y. Jamieson, S. L. Aeilts, K. C. Hultzsch, R. R. Schrock, A. H. Hoveyda Organometallics, 2004, 23, 1997.
92. “Supported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis,” S. J. Dolman, K. C. Hultzsch, F. Pezet, X. Teng, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc., 2004, 126, 10945.
91. “Enantioselective Synthesis of Cyclic Allylboronates by Mo-catalyzed Asymmetric Ring-Closing Metathesis (ARCM). A One-Pot Protocol for Net Catalytic Enantioselective Cross Metathesis,” J. A. Jernelius, R. R. Schrock, A. H. Hoveyda Tetrahedron, 2004, 60, 7345.
90. “Cu-Catalyzed Asymmetric Allylic Alkylations of Aromatic and Aliphatic Phosphates with Alkylzinc Reagents. An Effective Method for Enantioselective Synthesis of Tertiary and Quaternary Carbons, ” M. A. Kacprzynski, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 10676.
89. “Ag-Catalyzed Asymmetric Mannich Reactions of Enol Ethers with Aryl, Alkyl, Alkenyl, and Alkynyl Imines,” N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 3734.
88. “Catalytic Homologation of Vinyltributylstannane to Allyltributylstannae by Mo(IV) Complexes in the Presence of Ethylene,” R. R. Schrock, M. Duval-Lungulescu, W. C. P. Tsang, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 1948.
87. “Mo-Catalyzed Asymmetric Olefin Metathesis in Target-Oriented Synthesis. Enantioselective Synthesis of (+)-Africanol,” G. S. Weatherhead, G. A. Cortez, R. R. Schrock, A. H. Hoveyda Proc. Nat. Acad. Sci. 2004, 101, 5805.
86. “Enantioselective Total Synthesis of Erogorgiaene: Applications of Asymmetric Cu-Catalyzed Conjugate Additions of Alkylzincs to Acyclic Enones,” R. R. Cesati, J. de Armas, A. H. Hoveyda J. Am. Chem. Soc. 2004, 126, 96.
85. “Enantioselective Synthesis of Cyclic Secondary Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis (ARCM),” S. J. Dolman, R. R. Schrock, A. H. Hoveyda Org. Lett. 2003, 5, 4899.
84. “Chiral Ru-Based Complexes for Asymmetric Olefin Metathesis: Enhancement of Catalytic Activity through Steric and Electronic Modifications”, J. J. Van Veldhuizen, D. G. Gillingham, S. B. Garber, O. Kataoka, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 12502.
83. “Three-Component Enantioselective Synthesis of Propargylamines through Zr-Catalyzed Additions of Alkyl Zinc Reagents to Alkynylimines,” L. C. Akullian, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 2003, 42, 4244.
82. “Enantioselective Synthesis of Propargylamines through Zr-Catalyzed Addition of Mixed Alkynylzinc Reagents to Arylimines,” J. F. Traverse, A. H. Hoveyda, M. L. Snapper Org. Lett. 2003, 5, 3273.
81. “Total Synthesis of Anti-HIV Chloropeptin I,” H. Deng, J-K. Jung, T. Liu, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 9032.
80. “Enantioselective Synthesis of α-Alkyl-β,γ-unsaturated Esters through Efficient Cu-Catalyzed Allylic Alkylations,” K. E. Murphy, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 4690.
79. “Efficient and Practical Ag-Catalyzed Cycloadditions between Arylimines and the Danishefsky Diene,” N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 4018.
78. “Cu-Catalyzed Enantioselective Conjugate Additions of Alkyl Zinc Reagents to Unsaturated N-Acyloxazolidinones Promoted by a Chiral Triamide Phosphane,” A. W. Hird, A. H. Hoveyda Angew. Chem., Int. Ed. 2003, 42, 1276.
77. “An Enantiomerically Pure Adamantylimido Molybdenym Alkylidene Complex. An Effective New Catalyst for Enantioselective Olefin Metathesis,” W. C. P. Tsang, J. A. Jernelius, G. A. Cortez, G. S. Weatherhead, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 2591.
76. “Alkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations,” W. C. P. Tsang, K. C. Hultzsch, J. B. Alexander, P. J. Bonitatebus, Jr., R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2003, 125, 2652.
75. “Zr-Catalyzed Diastereo- and Enantioselective Diene Cyclizations. An Unexpected Synthesis of Chiral Aldehydes,” S. J. Degrado, J. A. Adams, A. H. Hoveyda Inorg. Chim. Acta 2003, 345, 261.
74. “Efficient Cu-Catalyzed Asymmetric Conjugate Additions of Allylzincs to Trisubstituted Cyclic Enones,” S. J. Degrado, H. Mizutani, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 13362.
73. “Enhancement of Enantioselectivity by THF in Asymmetric Mo-Catalyzed Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Tertiary Ethers and Spirocycles,” X. Teng, D. R. Cefalo, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 10779.
72. “Cu–Catalyzed Enantioselective Conjugate Addition of Alkylzincs to Cyclic Nitroalkenes: Catalytic Asymmetric Synthesis of Cyclic α-Substituted Ketones,” C. A. Luchaco-Cullis, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 8192.
71. “Efficient Catalytic Enantioselective Synthesis of Unsaturated Amines: Preparation of Small- and Medium-Ring Cyclic Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis in the Absence of Solvent,” S. J. Dolman, E. S. Sattely, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 2002, 124, 6991.
70. “A Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring-Opening/Cross Metathesis in Air,” J. J. Van Veldhuizen, S. B. Garber, J. S. Kingsbury, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 4954.
69. “Enantioselective Synthesis of Medium Ring Heterocycles, Tertiary Ethers and Tertiary Alcohols by Mo-Catalyzed Ring-Closing Metathesis,” A. F. Kiely, J. A. Jernelius, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 2868.
68. “Olefins Turned Alkylating Agents: Diastereoselective Intramolecular Zr-Catalyzed Olefin Alkylations,” R. R. Cesati III, J. de Armas, A. H. Hoveyda Org. Lett. 2002, 4, 395.
67. “Aluminum-Catalyzed Asymmetric Addition of TMSCN to Aromatic and Aliphatic Ketones Promoted by an Easily Accessible and Recyclable Peptide Ligand,” H. Deng, M. P. Isler, M. L. Snapper, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20020315)41:63.0.CO;2-F”>Angew. Chem., Int. Ed. 2002, 41, 1009.
66. “The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis,” K. C. Hultszch, J. A. Jernelius, A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3773(20020215)41:43.0.CO;2-V”>Angew. Chem., Int. Ed. 2002, 41, 589.
65. “Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Acyclic Aliphatic Enones,” H. Mizutani, S. J. Degrado, A. H. Hoveyda J. Am. Chem. Soc. 2002, 124, 779.
64. “New Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3′-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands,” R. R. Schrock, J. Y. Jamieson, S. J. Dolman, S. A. Miller, P. J. Bonitatebus, A. H. Hoveyda Organometallics 2002, 21, 409.
63. “Evaluation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts for Asymmetric Olefin Metathesis Reactions that Contain 3,3′-Diphenyl- or 3,3′-Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of Unsubstituted Molybdacyclobutane Complexes,” W. C. P. Tsang, R. R. Schrock, A. H. Hoveyda Organometallics 2001, 20, 5658.
62. “Immobilization of Olefin Metathesis Catalysts on Monolithic Sol-Gel. Practical, Efficient and Easily Recyclable Catalysts for Organic and Combinatorial Synthesis,” J. S. Kingsbury, S. B. Garber, J. M. Giftos, B. L. Gray, M. M. Okamoto, R. A. Farrer, J. T. Fourkas, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20011119)40:223.0.CO;2-L”>Angew. Chem., Int. Ed. 2001, 40, 4251.
61. “Mechanism of Enantioselective Ti-Catalyzed Strecker Reaction: Peptide-Based Metal Complexes as Bifunctional Catalysts,” N. S. Josephson, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 11594.
60. “Three-Component Catalytic Asymmetric Synthesis of Aliphatic Amines,” J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper J. Am. Chem. Soc. 2001, 123, 10409.
59. “Molybdenum Imido Alkylidene Complexes Containing Biphen Ligands That Have Silyl Groups Attached through the 6 and 6′ Methyl Group Carbon Atoms,” K. C. Hultszch, P. J. Bonitatebus, J. Jernelius, R. R. Schrock, A. H. Hoveyda Organometallics 2001, 20, 4705.
58. “Zr-Catalyzed Electrophilic Carbomagnesation of Aryl Olefins. Mechanism-Based Control of Zr-Mg Ligand Exchange,” J. de Armas, A. H. Hoveyda Org. Lett. 2001, 3, 2097.
57. “Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes,” D. S. La, E. S. Sattely, J. G. Ford, R. R. Schrock, A. H. Hoveyda J. Am.Chem. Soc. 2001, 123, 7767.
56. “Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Cu-Catalyzed Allylic Substitutions,” C. A. Luchaco-Cullis, H. Mizutani, K. E. Murphy, A. H. Hoveyda <a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-T”>Angew. Chem., Int. Ed. 2001, 40, 1456.
55. “A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis,” S. L. Aeilts, D. R. Cefalo, P. J. Bonitatebus, Jr., J. H. Houser, A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-G”>Angew. Chem., Int. Ed. 2001, 40, 1452.
54. “Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers by Mo-Catalyzed Olefin Metathesis,” D. R. Cefalo, A. F. Kiely, M. Wuchrer. J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 3139.
53. “Cross-Metathesis Reaction. Generation of Highly Functionalized Olefins from Unsaturated Alcohols,” J. Cossy, S. BouzBouz, A. H. Hoveyda J. Organomet. Chem. 2001, 634, 216.
52. “Enantioselective Synthesis of Arylamines Through Zr-Catalyzed Addition of Dialkylzincs to Imines. Reaction Development by Screening of Parallel Libraries,” J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper J. Am. Chem. Soc. 2001, 123, 984.
51. “Modular Peptide-Based Phosphine Ligands in Asymmetric Catalysis: Efficient and Enantioselective Cu-Catalyzed Conjugate Additions to Five-, and Six- and Seven-Membered Cyclic Enones,” S. J. Degrado, H. Mizutani, A. H. Hoveyda J. Am. Chem. Soc. 2001, 123, 755.
50. “Synthesis of Molybdenum Imido Alkylidene Complexes that Contain 3,3′-Dialkyl-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2,2′-diolates (Alkyl = t-Bu or Adamantyl). Catalysts for Enantioselective Olefin Metathesis Reactions,” J. B. Alexander, R. R. Schrock, W. M. Davis, W., K. C. Hultzsh, A. H. Hoveyda, J. H. Houser, Organometallics 2000, 19, 3700.
49. “Modular Mo-Based Catalysts for Efficient Asymmetric Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Ethers and Acetals,” G. S. Weatherhead, J. H. Houser, J. G. Ford, J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda Tetrahedron Lett. 2000, 41, 9553. (Special issue in celebration of the 80th birthday of Professor Harry H. Wasserman)
48. “Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts,” S. B. Garber, J. S. Kingsbury, B. L. Gray, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 8168.
47. “Zr-Catalyzed Olefin Alkylations and Allylic Substitution Reactions with Electrophiles,” J. de Armas, S. P. Kolis, A. Hoveyda J. Am. Chem. Soc. 2000, 122, 5977.
46.“Ti-Catalyzed Regio- and Enantioselective Synthesis of Unsaturated α-Amino Nitriles, Amides and Acids. Catalyst Identification through Screening of Parallel Libraries,” J. R. Porter, W. G. Wirschun, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 2657.
45. “Synthesis of Molybdenum Imido Alkylidene Complexes Containing N,N’-Disubstituted 2,2′-Bisamido-1,1′-binaphthyl Ligands,” J. Y. Jamieson, R. R. Schrock, W. M. Davis, P. J. Bonitatebus, S. S. Zhu, A. H. Hoveyda Organometallics 2000, 19, 925.
44. “Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,” G. S. Weatherhead, G. J. Ford, E. J. Alexanian, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 2000, 122, 1828.
43. “Zr-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis,” J. A. Adams, J. G. Ford, P. J. Stamatos, A. H. Hoveyda J. Org. Chem 1999, 64, 9690.
42. “Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,” D. S. La, J. G. Ford, E. S. Sattely, P. J. Bonitatebus, R. R. Schrock, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 11603.
41. “Chiral Mo-Binol Complexes: Activity, Synthesis, and Structure. Efficient Enantioselective Six-Membered Ring Synthesis through Catalytic Metathesis,” S. S. Zhu, D. R. Cefalo, D. S. La, J. Y. Jamieson, W. M. Davis, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1999, 121, 8251.
40. “Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids, ” C. A. Krueger, K. W. Kuntz, C. D. Dzierba, W. G. Wirschun, J. D. Gleason, M. L. Snapper, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 4284.
39. “Stereoselective Chelate-Controlled Addition of Grignard Reagents to Unsaturated Medium-Ring Heterocycles,” J. A. Adams, N. M. Heron, A. M. Koss, A. H. Hoveyda J. Org. Chem. 1999, 64, 854.
38. “Diastereoselective Intramolecular Cycloaddition of Vinylsilanes and Silyl Nitronates. Effective Control of Remote Acyclic Asymmetry,” D. G. J. Young, E. Gomez-Bengoa, A. H. Hoveyda J. Org. Chem. 1999, 64, 692.
37. “A Recyclable Ru-Based Metathesis Catalyst,” J. S. Kingsbury, J. P. A. Harrity, P. J. Bonitatebus, A. H. Hoveyda J. Am. Chem. Soc. 1999, 121, 791.
36. “Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing Metathesis,” D. S. La, J. B. Alexander, D. R. Cefalo, D. D. Graf, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1998, 120, 9720.
35. “Zr-Catalyzed Kinetic Resolution of Allylic Ethers and Mo-Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)-Nebivolol,” C. W. Johannes, M. S. Visser, G. S. Weatherhead, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 8340.
34. “Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen-Mo Complex,” J. B. Alexander, D. S. La, D. R. Cefalo, A. H. Hoveyda, R. R. Schrock J. Am. Chem. Soc. 1998, 120, 4041.
33. “Ni-Catalyzed Asymmetric Addition of Grignard Reagents to Unsaturated Cyclic Acetals. The Influence of Added Phosphine on Enantioselectivity,” E. Gomez-Bengoa, N. M. Heron, M. T. Didiuk, C. A. Luchaco, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 7649.
32. “Chromenes through Metal-Catalyzed Reactions of Styrenyl Ethers. Mechanism and Utility in Synthesis,” J. P. A. Harrity, D. S. La, D. R. Cefalo, M. S. Visser, A. H. Hoveyda J. Am. Chem. Soc. 1998, 120, 2343.
31. “Phosphine-Directed Stereo- & Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers,” M. T. Didiuk, J. P. Morken, A. H. Hoveyda Tetrahedron 1998, 54, 1117.
30. “Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1),” Z. Xu, C. W. Johannes, A. F. Houri, D. S. La, D. A. Cogan, G. E. Hofilena, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 10302.
29. “Stereoselective Heteroatom-Assisted Allylic Alkylation of Cyclic Ethers With Grignard Reagents. A Convenient Route to Enantiomerically Pure Carbocycles,” N. M. Heron, J. A. Adams, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 6205.
28. “Search for Chiral Catalysts Through Ligand Diversity: Substrate-Specific Catalysts and Ligand Screening on Solid Support,” K. D. Shimizu, B. M. Cole, C. A. Krueger, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 1997, 36, 1704.
27. “Synthesis of Amino Sugars Through a Highly Diastereoselective Dipolar Cycloaddition. Enantioselective Synthesis of the Carbohydrate Segment of Sch 38516,” Z. Xu, C. W. Johannes, D. S. La, G. E. Hofilena, A. H. Hoveyda Tetrahedron 1997, 53, 16377.
26. “Ru-Catalyzed Rearrangement of Styrenyl Ethers. Enantioselective Synthesis of Chromenes Through Zr- and Ru-Catalyzed Processes,” J. P. A. Harrity, M. S. Visser, J. D. Gleason, A. H. Hoveyda J. Am. Chem. Soc. 1997, 119, 1488.
25. “Enantioselective Total Synthesis of Antifungal Agent Sch 38516,” Z. Xu, C. W. Johannes, S. S. Salman, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 10926.
24. “Discovery of Chiral Catalysts through Ligand Diversity: Ti-Catalyzed Enantioselective Addition of TMSCN to meso Epoxides,” B. M. Cole, K. D. Shimizu, C. A. Kruger, J. P. A. Harrity, M. L. Snapper, A. H. Hoveyda Angew. Chem., Int. Ed. 1996, 35, 1668.
23. “Directed Regioselective Ni-Catalyzed Alkylation and Hydride Addition of Allylic Ethers. A Remarkable Turnover in Regioselectivity,” J. P. Morken, M. T. Didiuk, A. H. Hoveyda Tetrahedron Lett. 1996, 37, 3613.
22. “Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems,” M. S. Visser, J. P. A. Harrity, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 3779.
21. “Catalytic and Enantioselective Route to Medium-Ring Heterocycles. Asymmetric Zirconium-Catalyzed Ethylmagnesation of Seven- and Eight-Membered Rings,” M. S. Visser, N. M. Heron, M. T. Didiuk, J. F. Sagal, A. H. Hoveyda J. Am. Chem. Soc. 1996, 118, 4291.
20. “Highly Diastereoselective Hydrosilation Reactions. Spirocyclic Siloxanes: Sources of Si-Based Lewis Acids,” D. G. J. Young, M. R. Hale, A. H. Hoveyda Tetrahedron Lett. 1996, 37, 827.
19. “Directed Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers,” M. T. Didiuk, J. P. Morken, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 7273.
18. “Cascade Catalysis in Synthesis. An Enantioselective Route to Sch 38516 (and Fluvirucin B1) Aglycon Macrolactam,” A. F. Houri, Z. Xu, D. A. Cogan, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 2943.
17. “Enantio-, Diastereo-, and Regioselective Zirconium-Catalyzed Carbomagnesation of Cyclic Ethers with Higher Alkyls of Magnesium. Utility in Synthesis and Mechanistic Implications,” M. T. Didiuk, C. W. Johannes, J. P. Morken, A. H. Hoveyda J. Am. Chem. Soc. 1995, 117, 7097.
16. “Zirconocene-Catalyzed Kinetic Resolution of Dihydrofurans,” M. S. Visser, A. H. Hoveyda Tetrahedron 1995, 51, 4383.
15. “Diastereoselective Heteroatom-Directed Conjugate Addition of Silylcuprate Reagents to Unsaturated Carbonyls. A Stereoselective Route to β-Carbonyl Siloxanes,” M. R. Hale, A. H. Hoveyda J. Org. Chem. 1994, 59, 4370.
14. “Zirconium-Catalyzed Kinetic Resolution of Pyrans,” J. P. Morken, M. T. Didiuk, M. S. Visser, A. H. Hoveyda J. Am. Chem. Soc. 1994, 116, 3123.
13. “Zirconium-Catalyzed Asymmetric Carbomagnesation,” J. P. Morken, M. T. Didiuk, A. H. Hoveyda J. Am. Chem. Soc. 1993, 115, 6997.
12. “Regio- and Stereoselective Carbon-Carbon Bond Formation through Transition Metal Catalysis. The Influence of Catalyst Chirality on Selective Ethylmagnesation of Chiral, Nonracemic Alcohols and Ethers,” A. H. Hoveyda, J. P. Morken J. Org. Chem. 1993, 58, 4237.
11. “Zirconium-Catalyzed Ethylmagnesation of Hydroxylated Terminal Alkenes; A Catalytic and Diastereoselective Carbon-Carbon Bond-Forming Reaction,” A. F. Houri, M. T. Didiuk, Z. Xu, N. R. Horan, A. H. Hoveyda J. Am. Chem. Soc. 1993, 115, 6614.
10. “On the Mechanism of the Zirconium-Catalyzed Carbomagnesation Reaction. Efficient and Selective Catalytic Carbomagnesation with Higher Alkyls of Magnesium,” A. H. Hoveyda, J. P. Morken, A. F. Houri, Z. Xu J. Am. Chem. Soc. 1992, 114, 6692.
9. “Rhodium (I)- and Iridium (I)-Catalyzed Hydroboration Reactions: Scope and Synthetic Applications,” D. A. Evans, G. C. Fu, A. H. Hoveyda J. Am. Chem. Soc. 1992, 114, 6671.
8. “Siloxanes: Versatile Templates for Acyclic Stereocontrol. Synthesis of the C27-C33 Segment of Rapamycin,” M. R. Hale, A. H. Hoveyda J. Org. Chem. 1992, 57, 1643.
7. “Stereoselective Zirconium-Catalyzed Ethylmagnesation of Homoallylic Alcohols and Ethers. The Influence of Internal Lewis Bases on Substrate Reactivity,” A. H. Hoveyda, Z. Xu, J. P. Morken, A. F. Houri J. Am. Chem. Soc. 1991, 113, 8950.
6. “Stereoselective Formation of Carbon-Carbon Bonds Through Metal Catalysis. The Zirconium-Catalyzed Ethylmagnesation Reaction,” A. H. Hoveyda, Z. Xu J. Am. Chem. Soc. 1991, 113, 5079.
5. “Samarium-Catalyzed Intramolecular Tishchenko Reduction of β-Hydroxy Ketones. A Stereoselective Approach to the Synthesis of Differentiated Anti 1,3-Diol Monoesters,” D. A. Evans, A. H. Hoveyda J. Am. Chem. Soc. 1990, 112, 6447.
4. “Reduction of β-Hydroxy Ketones with Catecholborane. A Stereoselective Approach to the Synthesis of Syn-1,3-Diols,” D. A. Evans, A. H. Hoveyda J. Org. Chem. 1990, 55, 5190.
3. “The Rhodium(I)-Catalyzed Hydroboration of Olefins. The Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems,” D. A. Evans, G. C. Fu, A. H. Hoveyda J. Am. Chem. Soc. 1988, 110, 6917.
2. “Synthetic Studies of the Furan-Carbonyl Photocycloaddition Reaction. A Total Synthesis of (±)-Avenaciolide,” S. L. Schreiber, A. H. Hoveyda J. Am. Chem. Soc. 1984, 106, 7200.
1. “A Photochemical Route to the Formation of Threo Aldols,” S. L. Schreiber, A. H. Hoveyda, H-J. Wu J. Am. Chem. Soc. 1983, 105, 660.
Reviews, Perspectives, & Concept Articles
“Taking Olefin Metathesis to the Limit: Stereocontrolled Synthesis of Trisubstituted Alkenes,” A. H. Hoveyda, C. Qin, X. Z. Sui, Q. Liu, X. Li, A. Nikbakht Acc. Chem. Res. 2023, 56, 2426.
“Catalytic and Stereoselective Transformations with Easily Accessible and Purchasable Allyl and Alkenyl Fluorides,” P. H. S. Paioti, S. A. Gonsales, S. Xu, A. Nikbakht, D. C. Fager, Q. Liu, A. H. Hoveyda Angew. Chem. Int. Ed. 2022, e202208742.
“Impact of Ethylene on Efficiency and Stereocontrol in Olefin Metathesis: When to Add It, When to Remove It,and When to Avoid It,” A. H. Hoveyda, Z. Liu, C. Qin, T. Koengeter, Y. Mu Angew. Chem. Int. Ed. 2020, 59, 22324.
“Sulfonate N-Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective C–C, C–B, C–H, and C–Si Bond Formation,” A. H. Hoveyda, Y. Zhou, Y. Shi, K. Brown, H. Wu, S. Torker Angew. Chem. Int. Ed. 2020, 59, 21304.
“Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes,” A. H. Hoveyda, M. J. Koh, K. Lee, J. Lee, in Organic Syntheses, S. E. Denmark, D. Hall, Eds; 2020, Vol 100, 959.
“Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems,” F. Romiti, J. del Pozo, P. H. S. Paioti, S. A. Gonsales, X. Li, F. W. W. Hartrampf, A. H. Hoveyda J. Am. Chem. Soc. 2019, 141, 17952.
“Organoaluminum Compounds in Catalytic Enantioselective C–C Bond Forming Reactions,” K. P. McGrath, A. H. Hoveyda in The Chemistry of Organoaluminum Compounds., Z. Rappoport, I. Marek, Eds.; Wiley, Hoboken, 2017.
“Activation of B–B and B–Si Bonds and Synthesis of Organoboron and Organosilicon Compounds through Lewis Base Catalyzed Transformations,” A. Hoveyda, H. Wu, S. Radomkit, J. M. Garcia, F. Haeffner, K-S. Lee in Lewis Base Catalysis; E. Vedejs, S. E. Denmark. Eds.; VCH-Wiley, Weinheim, 2016, Vol 3, 967.
“Catalyst-Controlled Stereoselective Olefin Metathesis,” A. H. Hoveyda, R. K. M. Khan, S. Torker, S. J. Malcolmson, Handbook of Metathesis (Second Edition), R. H. Grubbs, D. J. O’Leary, Eds.; VCH-Wiley, Weinheim, 2015, Vol 2, 503.
“Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity,” A. H. Hoveyda J. Org. Chem. 2014, 79, 4763.
“Dichloro[[2-(1-methylethoxy-O)phenyl]- methylene](tricyclohexylphosphine) Ruthenium,” S. B. Garber, A. H. Hoveyda, R. K. M. Khan, T. J. Mann, e-EROS Encyclopedia of Reagents for Organic Synthesis
“Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin Angew. Chem. Int. Ed. 2010, 49, 34.
“Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in Metathesis in Natural Product Synthesis; Cossy, J. Ed.; Wiley-VCH, 2010, 343, (Chapter 12).
“Catalytic Enantioselective Olefin Metathesis,” A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in Catalytic Asymmetric Synthesis; Ojima, I. Ed.; Wiley-VCH, 2010, 739 (Chapter 8E).
“Molybdenum,[(S)-3,3′-bis(1,1-dimethylethyl)-5,5′,6,6′-tetramethyl[1,1′-biphenyl]-2,2′-diolato(2-)-kO,kO’]-2-methyl-2-phenylpropylidene)[tricyclo[3.3.1.13,7]decan-1-aminato(2-)],” S. J. Malcolmson, A. H. Hoveyda, R. R. Schrock, (Encyclopedia of Reagents for Organic Synthesis, Second Edition; Paquette, Crich, Fuchs, Molander, Eds.; 1765-1768); Wiley-VCH: Weinheim, 2009.
“The Remarkable Metal-catalysed Olefin Metathesis Reaction,” A. H. Hoveyda, A. R. Zhugralin Nature 2007, 450, 243.
“Small Peptides as Ligands for Catalytic Asymmetric Alkylations of Olefins. Rational Design of Catalysts or of Searches that Lead to Them?,” A. H. Hoveyda, A. W. Hird, M. A. Kacprzynski Chem. Commun. 2004, 16, 1779.
“Ru Complexes Bearing Bidentate Carbenes: From Innocent Curiosity to Uniquely Effective Catalysts for Olefin Metathesis,” A. H. Hoveyda, D. G. Gillingham, J. J. Van Veldhuizen, O. Kataoka, S. B. Garber, J. S. Kingsbury, J. P. A. Harrity Org. Biomol. Chem. 2004, 2, 8.
“Combinatorial Approaches,” A. H. Hoveyda, K. E. Murphy in Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 2004, 171 (Supplement to Chapter 39).
“Metathesis Reactions,” A. H. Hoveyda, R. R. Schrock in Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 2004, 207 (Chapter 44).
“Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin-Metathesis Catalysts,” R. R. Schrock, A. H. Hoveyda Angew. Chem. Int. Ed. 2003, 42, 4592.
“Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda, R. R. Schrock in Handbook of Metathesis, R. H. Grubbs, Ed.; VCH-Wiley, Weinhein, 2003, 128 (Vol. 2).
“Polymer-Supported Olefin Metathesis Catalysts for Organic and Combinatorial Synthesis,” J. S. Kingsbury and A. H. Hoveyda in Polymeric Materials in Organic Synthesis and Catalysis, M. R. Buchmeiser, Ed.; VCH-Wiley, Weinheim, 2003, 467.
“Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda in Organic Synthesis Highlights V, H-G. Schmalz and T. Wirth, Eds; VCH-Wiley, Weinheim, 2003, 210.
“Chiral Zirconium Catalysts for Enantioselective Synthesis” A. H. Hoveyda in The Chemistry of Titanium and Zirconium Complexes, I. Marek, Ed.; VCH-Wiley, New York, 2002, 180.
“Diversity-Based Approaches to Chiral Catalyst Discovery,” A. H. Hoveyda in The Handbook of Combinatorial Chemistry, K. C. Nicolaou, R. Hanko, W. Hartwig, Eds.; VCH-Wiley, Weinheim, 2002, 991.
“Catalytic Asymmetric Olefin Metathesis,” A. H. Hoveyda, R. R. Schrock <a href="https://doi.org/10.1002/1521-3765(20010302)7:53.0.CO;2-3″>Chem. Eur. J. 2001, 7, 945.
. “High-Throughput Screening of Titanium-Tripeptide Schiff Base Complexes for Catalytic Asymmetric Addition of Trimethylsilylcyanide to Epoxides and Imines,” K. W. Kuntz, M. L. Snapper, A. H. Hoveyda in High-Throughput Synthesis, Sucholeiki, I., Ed.; Marcel Dekker: New York, 2000, 283.
“Combinatorial Approaches to Chiral Catalyst Discovery,” M. L. Snapper and A. H. Hoveyda in Combinatorial Chemistry, Fenniri, H. Ed.; Oxford, 2000, 433.
. “Asymmetric Catalysis in Target-Oriented Synthesis,” A. H. Hoveyda in Stimulating Concepts in Chemistry, Stoddart, F. J., Shibasaki, M., Vogtle, F., Eds; VCH: Weinheim, 2000, 145.
“Stereoselective Addition of Grignard Reagents to Alkenes,” A. H. Hoveyda, N. M. Heron, J. A. Adams in Grignard Reagents: New Developments, Richey, H. G., Ed.; John Wiley and Sons: New York, 2000, 107.
“Combinatorial Catalysis: Identification of Potent Chiral Catalysts Through Fluorescent Bead Signaling,” A. H. Hoveyda Chem. & Biol. 1999, 6, R305.
“Carbometallation of Carbon-Carbon Double Bonds,” A. H. Hoveyda, N. M. Heron in Comprehensive Asmmetric Catalysis, Vol. III, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer-Verlag, 1999, 431.
“Combinatorial Approaches,” K. D. Shimizu, M. L. Snapper, A. H. Hoveyda in Comprehensive Asmmetric Catalysis, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer, 1999, 1389 (Chapter 39).
“Combinatorial Catalyst Discovery,” K. W. Kuntz, M. L. Snapper, A. H. Hoveyda Curr. Opinions in Chem. & Biol. 1999, 3, 313.
“Metal-Catalyzed Kinetic Resolution Processes,” A. H. Hoveyda, M. T. Didiuk Curr. Org. Chem. 1998, 2, 489.
“High-Throughput Strategies for the Discovery of Catalysts,” K. D. Shimizu, M. L. Snapper, A. H. Hoveyda <a href="https://doi.org/10.1002/(SICI)1521-3765(19981002)4:103.0.CO;2-D”>Chem., Eur. J. 1998, 4, 1885.
“Catalyst Discovery Through Combinatorial Chemistry,” A. H. Hoveyda Chemistry & Biology 1998, 5, R187.
“Catalytic Ring-Closing Metathesis and the Development of Enantioselective Processes,” A. H. Hoveyda in Metathesis, Furstner, A., Ed.; Springer: Berlin, 1998, 105.
“Chiral Titanocenes and Zirconocenes in Synthesis,” A. H. Hoveyda and J. P. Morken in Metallocenes, Togni, A.; Halterman R., Eds.; VCH: Weinheim; 1998, Vol. 2, 625.
“Catalytic Enantioselective Addition of Grignard Reagents to Olefins,” A. H. Hoveyda in Transition Metals for Fine Chemicals and Organic Synthesis, Bolm, C. Ed.; VCH: Weinheim, 1998, 195.
“Enantioselective C-C and C-H Bond Formation Mediated or Catalyzed by Chiral ebthi Complexes of Titanium and Zirconium,” A. H. Hoveyda, J. P. Morken Angew. Chem. Int. Ed. 1996, 35, 1263.
“Substrate-Directable Chemical Reactions,” A. H. Hoveyda, D. A. Evans, G. C. Fu Chem. Rev. 1993, 93, 1307.
Non-Research Articles
- “Primo Levi’s The Periodic Table. A Search for Patterns in Times Past,” A. H. Hoveyda, Angew. Chem., Int. Ed. 2004, 43, 6592.
- “Striving for Scientific Nirvana,” A. H. Hoveyda, Chemical & Engineering News 2001, 79, 198.
Patents
- “Synthesis of Z-Alkenyl Halides Through Stereoselective Olefin Methathesis,” 2017, Patent Number US 9,850,268.
- “Z-Selective Ring-Closing Metathesis Reactions,” 2017, Patent Number US 9,771,386.
- “Catalysts for Efficient Z-Selective Metathesis,” 2017, Patent Number US 14,303,523.
- “Z-Selective Coupling of Terminal Olefins,” 2017, Patent Number US 9,713,808.
- “Unique Chiral-at-Metal Catalysts for Remarkably Efficient and Exceptionally Enantioslecetive Olefin Metathesis,” 2017, Patent Number US 9,687,834.
- “Z-Selective Ring-Closing Metathesis Reactions,” 2016, Patent Number US 9,446,394.
- “Tungsten Oxo Alkylidene Complexes for Z Selective Olefin Metathesis,” 2015, Patent Number US 9,085,595.
- “High Z-Selective Olefin Metathesis,” 2015, Patent Number US 9,079,173.
- “Simple Organic Molecules as Catalysts for Practical and Enantioselective Synthesis of Amines and Alcohols,” 2015, Patent Number US 2015/0057451.
- “Efficient Methods for Z– or cis-Selective Cross-Metathesis,” 2013, Patent Number US 8,598,400.
- “Highly Z-Selective Olefin Metathesis,” 2013, Patent Number US 8,362,311.
- “Complexes for Use in Metathesis Reactions,” 2013, Patent Number US 8,546,500.
- “Efficient Methods for Z– or cis-Selective Cross-Metathesis,” 2013, Patent Number US 8,552,242.
- “Catalysts and Processes for the Formation of Terminal Olefins by Ethenolysis,” 2012, Patent Number US 8,222,469.
- “Catalysts for Metathesis Including Enantioselective Olefin Metathesis, And Related Methods,” 2009, Patent Number International WO 2009/094201.
- “Recyclable Metathesis Catalysts,” 2010, Patent Number US 7,723,255.
- “Recyclable Metathesis Catalysts,” 2005, Patent Number US 6,921,735.
- “Recyclable Chiral Metathesis Catalysts,” 2005, Patent Number US 6,939,982.
- “Chiral Cyanoamines and Methods of Preparation,” 2004, Patent Number US 6,693,168.
- “Asymmetric Ring-Closing Metathesis Reactions Involving Achiral and Meso Substrates,” 2002, Patent Number US 6,346,652.