Publications

 

2024

Capone, F., Muntada, O., Ramirez, J., Esplandiu, M., Dedryvere, R., Grimaud, A., Lassalle-Kaiser, B., Ceolin, D., Perez-Murano, F., Rueff, J., Fraxedas, J.
Development of hard X-ray photoelectron spectroscopy in liquid cells using optimized microfabricated silicon nitride membranes
Journal of Synchrotron Radiation, 2024, 31, 6

Pandya, R., Dorchies, F., Romanin, D., Lemineur, J., Kanoufi, F., Gigan, S., Chin, A., Aguiar, H., Grimaud, A.
Concurrent oxygen evolution reaction pathways revealed by high-speed compressive Raman imaging
Nature Communications, 2024, 15, 8362

Titirici, M.-M., Johansson, P., Crespo Ribadeneyra, M., Au, H., Innocenti, A., Passerini, S., Petavratzi, E., Lusty, P., Ahlberg Tidblad, A., Naylor, A. J., Younesi, R., Chart, Y. A., Aspinall, J., Pasta, M., Orive, J., Musuvadhi Babual, L., Reynaud, M., Latham, K. G., Hosaka, T., Komaba, S., Bitenc, J., Ponrouch, A., Zhang, H., Armand, M., Kerr, R., Howlett, P. C., Forsyth, M., Brown, J., Grimaud, A., Vilkman, M., Dermenci, K. B., Mousavihashemi, S., Berecibar, M., Marshall, J. E., McElroy, C. R., Kendrick, E., Safdar, T., Huang, C., Zanotto, F. M., Fernandez Troncoso, J., Zapata Dominguez, D., Alabdali, M., Vijay, U., Franco, A. A., Pazhaniswamy, S., Grant, P. S., Lopez Guzman, S., Fehse, M., Galceran Mestres, M., and Antuñano, N.
2024 roadmap for sustainable batteries
Journal of Physics: Energy, 2024, Accepted Manuscript

Dorchies, F., Serva, A., Sidos, A., Michot, L., Deschamps, M., Salanne, M., and Grimaud, A.
Correlating Substrate Reactivity at Electrified Interfaces with the Electrolyte Structure in Synthetically Relevant Organic Solvent/Water Mixtures
Journal of the American Chemical Society, 2024, 146, 25, 17495-17507

Richard, J., Solati, N., Singh, A., Meunier, V., Toda, Y., Grimaud, A., Perez, A., Laberty-Robert, C.
Functional Composite Separators with Cation-Trapping Abilities
ACS Applied Energy Materials, 2024, 7, 10, 4335-4346.

Dubouis, N., Ayme-Perrot, D., Degoulange, D., Grimaud, A. and Girault, H.
Alkaline Electrolyzers: Powering Industries and Overcoming Fundamental Challenges
Joule, 2024, 8, 4, P883-898

Brown, J., Karlsmo, M., Johansonn, P. and Grimaud, A.
Exploring the electrochemistry of PTCDI for aqueous lithium-ion batteries
Energy Storage Materials, 2024, 66, 103218.

Bonnassieux, S., Pandya, R., Skiba, D., Degoulange, D., Petit, D., Seem, P., Cowburn, R., Gallant, B., and Grimaud, A.
Revisting the driving force inducing phase separation in PEG-phosphate aqueous biphasic systems
Faraday Discussions, 2024, Advance Article.

Capone, F., Sottmann, J., Meunier, V., Perez Ramirez, L., Grimaud, A., Iadecolla, A., Scardamaglia, A., Rueff, J-P. and Dedryvere, R. 
Operando observation of the dynamic SEI formation on a carbonaceous electrode by Near-Ambiant Pressure XPS
Energy & Environmental Science, 2024, 17, 1509-1519.

2023

Degoulange, D., Rousse, G., and Grimaud, A. 
Two-steps halogen intercalation mechanism in dual-ion batteries enabled by aqueous biphasic systems
ACS Energy Letters, 2023, 8, 4397-4405.

Brown, J., Forero-Saboya, J., Baptiste, B., Karlsmo, M., Rousse, G. and Grimaud, A.
A guanidium salt as a chaotropic agent for aqueous battery electrolytes
Chemical Communications, 2023, 59, 12266-12269.

Duran, S., Grimaud, A., Faustini, M. and Peron J.
Porosity as a morphology marker to probe the degradation in IrO2 anode catalyst layers in proton exchange membrane water electrolyzers.
Chemistry of Materials, 2023, 35, 8590-8598.

Pandya, R., Valzania, L., Dorchies, F., Xia, F., McHugh, J., Mathieson, A., Tan, J.H., Parton, T.H., Godeffroy, L., Mazloomian, K., Miller, T.S., Kanoufi, F., De Volder, M., Tarascon, J.-M., Gigan, S., de Aguiar, H.B. and  Grimaud, A.
Three-dimensional operando optical imaging of particle and electrolyte heterogeneities inside Li-ion batteries, 
Nature Nanotechnology, 2023, online. (view-only version) Press release RS2E (French)

Meunier, V., Capone, F., Dedryvere, R. and Grimaud, A. 
Cascading degradations artificially improving the lifetime of Li-ion full cells using DMC-based highly concentrated electrolytes, 
Journal of The Electrochemical Society, 2023, 170, 060551.

Dorchiers, F. and Grimaud, A.
Fine tuning of electrosynthesis pathways by modulation of electrolyte solvation structure 
Chemical Science, 2013, 14, 7103-7113.

Zhu, Y., Droguet, L., Deng, J., Wang, X., Li, L., Dufil, Y., Deschannels, M., Jommongkol, R., Pareseecharoen, C., Grimaud, A., Tarascon, J.-M. and Fontaine, O.
Visualizing water reduction with diazonium grafting on a glassy carbon electrode surface in a water-in-salt electrolyte,
ACS Applied Materials & Interfaces, 2023, 15, 19, 23899-23907.

Degoulange, D., Pandya, R., Deschamps, M., Sikiba, D.A., Gallant, B.M., Gigan, S., de Aguiar, H.B. and Grimaud, A. 
Direct imaging of micrometer thick interfaces in salt-salt aqueous biphasic systems, 
Proceedings of the National Academy of Science USA, 2023, 120, 17, 2220662120. Press release RS2E (French)

Brown, J. and Grimaud A.
Proton-donating and chemistry-dependent buffering capability of amino acids for the hydrogen evolution reaction
Physical Chemistry Chemical Physics, 2023, 25, 8005-8012.

Gonell, F., Rousse, G., Odziomek, M., Baaziz, W., Ersen, O., Grimaud, A. and Sanchez, C. 
Nanostructured layered lithium iridates as electrocatalysts for improved oxygen evolution reaction
ACS Applied Nano Materials, 2023, 6, 4, 2577-2584.

Meunier, V., De Souza, M.L., Morcrette, M. and Grimaud, A. 
Design of workflows for cross-talk detection and lifetime deviation onset on Li-ion batteries
Joule, 2023, 7, 42-56.

Westhead, O. Spry, M., Bagger, A., Shen, Z., Yadegari, H., Favero, S., Tort, R., Tritici, M.-M., Ryan, M.P., Jervis, R., Aguadero, A., Regoutz, A., Grimaud, A. and Stephens, I.EL. 
The role of ion solvation in lithium mediated nitrogen reduction
Journal of Materials Chemistry A, 2023, 11, 12746-12758.

2022

Dorchies, F., Serva, A., Crevel, D., De Freitas, J., Kostopolous, N., Robert, M., Sel, O., Salanne, M. and Grimaud, A.
Controlling the hydrophilicity of the electrochemical interface to modulate the oxygen-atom transfer in electrocatalytic epoxidation reactions
Journal of the American Chemical Society, 2022, 144, 22734-22746.

Westhead, O., Tort, R., Spry, M., Rietbrock, J., Jervis, R., Grimaud, A., Bagger, A., and Stephens, I.EL. 
The origin of overpotential in lithium-mediated nitrogen reduction
Faraday Discussion, 2023, 243, 321-338.

Burton, T, Zhy, Y., Droguet, L., Niamlaem, M. Zigah, D., Grimaud A., Tarascon, J.-M. and Fontaine, O. 
Self-crosslinking poly(ethylene glycol) diglycidyl ether in water-in-salt electrolytes or minimal hydrogen evolution reactions and extended LiTFSI solubility
Journal of The Electrochemical Society, 2022, 169, 070533

Droguet, L., Courty, M., Fontaine, O., Tarascon, J.-M. and Grimaud, A. 
Determination of water reduction rates and activation energies in water-in-salt electrolytes
Journal of The Electrochemical Society, 2022, 169, 070510

Meunier, V., Leal de Souza, M., Morcrette, M. and Grimaud, A. 
Electrochemical protocols to assess the effects of dissolved transition metals in graphite/LiNiO2 cells performance
Journal of The Electrochemical Society, 2022, 169, 070506

Jovanov, Z. P., Lutz, L., Lozano, J., Holc, C., Gao, X., Grimaud, A., Tarascon, J.-M., Chen, Y., Johnson, L.R. and Bruce, P.G.
Competitive oxygen reduction pathways to superoxide and peroxide during sodium-oxygen battery discharge
Batteries & Supercaps, 2022, 5, e202200055

France-Lanord, A., Pietrucci, F., Saitta, A.M., Tarascon, J.-M., Grimaud, A. and Salanne, M. 
Chemical decomposition of the TFSI anion under aqueous basic conditions
Physical Review X Energy, 2022, 1, 013005

Brown, J. and Grimaud, A. 
With only a grain of salt
Nature Energy, 2022, 7, 126-127. News & Views 

Pandya, R., Dorchies, Romarin, D., Gigan, S., Chin, A.W., de Aguiar, H.B. and  Grimaud, A., 
Competing oxygen evolution reaction mechanisms by high-speed compressive Raman imaging, Arxiv. 

2021

Atkins. D, Ayerbe, E. Benayad, A., Capone, F., Capria, E., Castelli, I.E., Cekic-Laskovic, I., Ciria, R., Dudy, L., Edström, Johnson, M.R., Li, H., Lastra, J.M.G., Leal De Souza, M., Meunier, V., Morcrette, M., Reichert, H., Simon, P., Rueff, J.-P., Sottmann, J., Wenzel, W. and Grimaud, A. 
Understanding battery interfaces by combined characterization and simulation approaches: Challenges and perspectives
Advanced Energy Materials, 2021, 2102687

Fichtner. M, Edström, K., Ayarbe, E., Berecibar, M., Bhowmik, A., Castelli, I.E., Clark, S., Dominko, R., Erakca, M., Franco, A.A., Grimaud, A., Horstmann, B., Laft, A., Lorrmann, H., Meeus, M., Narayan, R., Pammer, F., Ruhland, J., Stein, H., Vegge, T. and Weil, M. 
Rechargeable batteries of the future – The state of the art from a BATTERY 2030+ perspective
Advanced Energy Materials, 2021, 2102904

Atkins. D, Capria, E., Edström, K., Famprikis, T., Grimaud, A., Jacquet, Q., Johnson, M., Matic, A., Norby, P., Reichert, H., Rueff, J.-P., Villevielle, C., Wagemaker, M. and Lyonnard, S. 
Accelerating battery characterization using neutron and synchrotron techniques: Toward a multi-modal and multi-scale standardized experimental workflow
Advanced Energy Materials, 2021, 2102694

Zhang, L., Grimaud, A., Schwiedernoch, R., Yesid Hernandez W., Ordomsky, V. and Naghavi, N. 
Quinone shuttling impels selective electrocatalytic alcohol oxidation: a hydrogen bonding-directed electrosynthesis
Journal of Electroanalytical Chemistry, 2021, 115820

Degoulange, D., Dubouis, N. and Grimaud, A.
Towards the understanding of water-in-salt electrolytes: Individual ion activities and liquid junction potentials in highly concentrated aqueous solutions
Journal of Chemical Physics, 2021, 155, 064701

Castelli, I.E., Arismendi-Arrieta, J., Bhowmik, A., Cekic-Laskovic, I., Clark, S., Dominko, R., Flores, E., Flowers, J., Frederiksen, K.U., Friis, J., Grimaud, A., Hansen, K.V., Hardwick, L.J., Hermansson, K., Königer, L., Lauritzen, H., Le Cras, F., Li, H., Lyonnard, S., Lormann, H., Marzari, N., Niedzicki, L., Pizzi, G., Rahmanian, F., Stein, H., Uhrin, M., Wenzel, W., Winter, M., Wölke, K. and Vegge, T. 
Data management plans: the importance of data management in the BIG-MAP project
Batteries & Supercaps, 2021, 4, 1803-1812

Lombardo, T., Duquesnoy, M., El-Bouysidy, H., Arén, F., Gallo-Bueno, A., Jorgensen, P.B., Bhowmik, A., Demortière, A., Ayerbe, E., Alcaide, F., Reynaud, M., Carrasco, J., Grimaud, A., Zhang, C., Vegge, T., Johansson, P. and Franco A.A. 
Artificial intelligence applied to battery research: Hype or reality?
Chemical Review, 2021, 122, 10899-10969

Marchandier, T., Dubouis, N., Fauth, F., Avdeev, M., Grimaud, A., Tarascon, J.M. and Rousse, G. 
Crystallographic and magnetic structures of the VI₃ and LiVI₃ van der Walls compounds
Physical Review B, 2021, 104, 014105

Dubouis, N., Marchandier, T., Rousse, G., Marchini, F., Fauth, F., Avdeev, M., Iadecola, A., Porcheron, B., Deschamps, M., Tarascon, J.M. and Grimaud, A. 
Enlarging insertion electrochemistry to soluble layered halides with superconcentrated electrolytes
Nature Materials, 2021, 20, 1545-1550

Droguet, L., Hobold, G.M., Lagadec, M.-F., Guo, R., Lethien, C., Hallot, M., Fontaine, O., Tarascon, J.M., Gallant, B.M. and Grimaud, A.
Can an inorganic coating serve as stable SEI for aqueous superconcentrated electrolytes?
ACS Energy Letters, 2021, 6, 2575-2583

Wu, T. Ren, X., Sun, Y., Sun, S., Xian, G., Scherer, G., Fisher, A., Mandler, A., Ager, J., Grimaud, A., Wang, J., Shen, C., Yang, H., Gracia, J., Gao, H.-J. and Xu, Z. 
Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation
Nature Communications, 2021, 12, 3634

Dubouis, N., France-Lanord, A., Brige, A., Salanne, M. and Grimaud, A. 
Anion specific effects drive the formation of Li-salt based aqueous biphasic systems
Journal of Physical Chemistry B, 2021,125, 5365-5372

El Bousiydy, H., Lombardo, T., Primo, E., Dusquenoy, M., Morcrette, M. Johansson, P. Simon, P., Grimaud, A. and Franco, A.A., 
What can text mining tell us about Li-ion battery researchers’ habits
Batteries & Supercaps, 2021, 4, 758-766

Serva, A., Dubouis, N., Grimaud, A. and Salanne, M. 
Confining water in ionic and organic solvents to tune its adsorption and reactivity at electrified interfaces
Accounts of Chemical Research, 2021, 54, 4, 1034-1042, 2021

Abdelghani Idriss, S., Dubouis, N., Grimaud, A., Stevens, P., Toussaint, G. and Colin, A. 
Effect of electrolyte on a gas evolution electrode
Scientific Reports, 2021, 11, 4677

Duan, Y., Lee, J.Y., Xi, S., Sun, Y., Ong, S.J.H., Chen, Y., Dou, S., Meng, F., Diao, C., Wang, X., Grimaud, A. and Xu, Z. 
Controllable cation leaching promoted surface reconstruction for water oxidation
Angewandte Chemie International Edition, 2021, 60, 7418-7425

2020

Grimaud, A. 
Acidic or basic oxides? Better together
Joule, 2020, 4, 2251-2253, Preview

Droguet, L., Grimaud, A., Fontaine, O. and J.-M. Tarascon 
Water in salt electrolytes (WiSE) for aqueous batteries: a long way to practicality
Advanced Energy Materials, 2020, 10, 2002440

Lagadec, M.-F and Grimaud, A. 
Water electrolyzers with closed and open systems
Nature Materials, 2020, 19, 1140-1150

Dubouis, N., Serva, A., Berthin, R., Jeanmairet, G., Porcheron, B. Salager, E., Salanne, M. and Grimaud, A. 
Tuning the water reduction through controlled nanoconfinement within an organic liquid matrix
Nature Catalysis, 2020, 3, 656-663

Ben Osman, M., Yin, W., Petenzi, T., Jousselme, B., Cornut, R. Raymondo-Pinero, E., Grimaud, A. and Laberty-Robert, C. 
Electrospun carbon fibers as air cathodes for aprotic Li-O₂: toward cathode design for enhanced capacity
Electrochemical Acta, 2020, 354, 136643

Azcarate, I., Yin, W., Methivier, C., Ribot, F., Laberty-Robert, C. and Grimaud, A. 
Assessing the oxidation behavior of EC:DMC based electrolyte on non-catalytically active surface
Journal of the Electrochemical Society, 2020, 167, 080530

Zhang, R., Pearce, P.E., Pimenta, V., Cabana, J., Li, H., Alves Dalla Corte, D., Abakumov, A., Rousse, G., Giaume, D., 
Deschamps, M. and Grimaud, A. 
First example of protonation of Ruddlesden-Popper Sr₂IrO₄: a route to improved water oxidation catalysts
Chemistry of Materials, 32, 3499-3509, 2020

Duan, Y., Dubouis, N., Huang, J., Alves Dalla Corte, D., Pimenta, V., Xu, Z. and Grimaud, A. 
Revealing the impact of electrolyte composition for Co-based water oxidation catalysts by the study of reaction kinetics parameters
ACS Catalysis, 10, 4160-4170, 2020

Yang, C., Rousse, G., Svane, K.L., Pearce, P.E., Abakumov, A.M., Deschamps, M., Cibin, G., Chadwick, A.V., Alves Dalla Corte, D., Hansen, H.A., Vegge, T., Tarascon, J.-M. and Grimaud, A. 
Cation insertion to break the activity/stability relationship for highly active oxygen evolution reaction catalyst
Nature Communications, 11, 1378, 2020

Yin, W., Grimaud, A., Rousse, G., Abakumov, A.M., Senyshyn, A., Zhang, L., Trabensinger, S., Iadecolla, A., Foix, D., Giaume, D., Tarascon, J.-M. 
Structural evolution at the oxidative and reductive limits in the first electrochemical cycle of Li_1.2Ni_0.13Mn_0.54Co_0.13O₂
Nature Communications, 11, 1252, 2020

2019

Dubouis, N., and Grimaud, A.
The hydrogen evolution reaction: from materials to interfacial descriptors
Chemical Science, 10, 9165-9181, 2019, Invited perspective

Zhang, R., Pearce, P.E., Duan, Y., Dubouis, N., Marchandier, T. and Grimaud, A. 
The importance of water structure and catalysts-electrolyte interface on the design of water splitting catalysts
Chemistry of Materials, 31, 8248-8259, 2019, Up and Coming Series, invited perspective (front cover)

Pearce, P.E., Yang, C., Iadecolla, A., Rodriguez-Carvajal, J., Rousse, G., Dedryvère, R., Abakumov, A.M., Giaume, D., Deschamps, M., Tarascon, J.-M. and Grimaud, A. 
Revealing the reactivity of the iridium trioxide intermediate for the oxygen evolution reaction in acidic media
Chemistry of Materials, 2019, 31, 5845-5855

Wu, T., Sun, S., Song, J., Xi, S., Du, Y., Bo, C., Sasangka, W.A., Liao, H., Gan, C.L., Zeng, L., Wang, H., Li, H. Grimaud, A. and Xu, J.J. 
Iron-facilitated dynamic active site generation on spinel CoAl₂O₄ with self-termination of surface reconstruction for water oxidation
Nature Catalysis, 2019, 2, 763-772

Dubouis, N. Park, C. Deschamps, M. Abdelghani-Idrissi, S. Colin, A. Salanne, M. Dzubiella, J. Grimaud, A. and Rotenberg, B.
Chasing aqueous biphasic systems from simple salts by exploring the LiTFSI/LiCl/H₂O phase diagram
ACS Central Science, 54, 640-643, 2019

Grimaud, A. 
Water electrolysis in search of performances… and therefore of electrocatalysts
L’Actualité chimique, mars 2019

Zhang, R., Dubouis, N., Ben Osman, M., Yin, W., Sougrati, M.T, Alves Dalla Corte, D., Giaume, D. and Grimaud, A.
Dissolution/precipitation equilibrium on the surface of iridium-based perovskites as oxygen evolution reaction catalysts in acidic media
Angewandte Chemie International Edition, 58, 4571-4575, 2019

Duan, Y., Sun, S., Sun, Y., Xi, S. Chi, X. Zhang, Q., Ren, X., Wang, J., Jun Hoong Ong, S., Du, Y., Gu, L., Grimaud, A. and Xu, Z.J. 
Mastering surface reconstruction of metastable spinel oxides for better water oxidation
Advanced Materials, 31, 1807898, 2019

2018

Dubouis, N., Serva, A., Salager, E., Deschamps, M., Salanne, M. and Grimaud, A. 
The fate of water at the electrochemical interfaces: electrochemical behavior of free water vs. coordinating water
Journal of Physical Chemistry Letters, 9, 6683-6688, 2018

Yang, C., Batuk, M., Jacquet, Q., Rousse, G., Yin, W., Zhang, L., Hadermann, J., Abakumov, A.M., Cibin, G., Chadwick, A., Tarascon, J.-M and Grimaud, A. 
Revealing the pH dependent activities and surface instabilities for Ni-based electrocatalysts during the oxygen evolution reaction
ACS Energy Letters, 3, 2884-2890, 2018

Dubouis, N., Lemaire, P., Mirvaux, B., Salager, E., Deschamps, M. and Grimaud, A. 
The role of hydrogen evolution reaction on the solid-electrolyte-interphase formation mechanism for “Water-in-Salt” electrolytes
Energy and Environmental Science, 11, 3491-3499, 2018

Yin, W., Mariyappan, S., Grimaud, A. and Tarascon, J.-M.
Rotating ring disk electrode for monitoring the oxygen release at high potentials in Li-rich layered oxides
Journal of the Electrochemical Society, 165, A3326-A3333, 2018

Azcarate, I., Costentin, C., Methivier, C., Robert-Laberty, C. and Grimaud, A.
Electron transfer at the metal oxide/electrolyte interface: A simple methodology for quantitative kinetics evaluation
Journal of Physical Chemistry C, 122, 12761-12770, 2018

Grimaud, A. Iadecola, A., Batuk, D., Saubanère, M., Abakumov, A.M., Freeland, J.W., Cabana, J., Li, H., Doublet, M.-L., Rousse, G. and Tarascon, J.-M 
Chemical activity of the peroxide/oxide redox couple: case study of Ba₅Ru₂O₁₁ in aqueous and organic solvents
Chemistry of Materials, 30, 3882-3893, 2018

Grimaud, A. 
Electrocatalysts: an eye on surface changes
Nature Catalysis, 1, 242-243, 2018

Grimaud, A. Yin, W., Lepoivre, F. and Tarascon, J.-M 
Controlling the specific CO₂ adsorption on electrochemically formed metallic copper surfaces
Journal of the Electrochemical Society, 156, H163-H169, 2018       

Yin, W., Grimaud, A., Azcarate, I., Yang, C. and Tarascon, J.-M.
The electrochemical reduction of CO₂ mediated by quinone derivatives: Implication for Li-CO₂ battery
Journal of Physical Chemistry C, 122, 6546-6554, 2018

Lutz, L., Dachraoui, W., Demortière, A., Johnson, L.R., Bruce, P., Grimaud, A. and Tarascon, J.-M. 
Operando monitoring of the solution-mediated discharge and charge processes in a Na-O₂ battery using liquid-electrochemical TEM
Nano Letters, 18, 1280-1289, 2018

Dubouis, N., Yang, C., Beer, R., Ries, L. Voiry, D. and Grimaud, A. 
Interfacial interactions as an electrochemical tool to understand Mo-based catalysts for the hydrogen evolution reaction
ACS Catalysis, 8, 828-836, 2018

Lutz, L., Alves Dalla Corte, D., Chen, Y., Batuk, D., Johnson, L.R., Abakumov, A., Yate, L., Azaceta, E., Bruce, P.G., Tarascon, J.-M. and Grimaud, A. 
The role of the electrode surface in Na-air batteries; insights in electro-chemical product formation and chemical growth of NaO₂
Advanced Energy Materials, 8, 1701581, 2018

2017

Yang, C., Laberty-Robert, C., Batuk, D., Cibin, A., Chadwick, A., Pimenta, V., Yin, W., Zhang, L., Tarascon, J.-M. and Grimaud, A. 
Phosphate ion functionalization of perovskite surfaces for enhanced oxygen evolution reaction
Journal of Physical Chemistry Letters, 8, 3466-3472, 2017

Lutz, L., Alves Dalla Corte, D., Tang, M., Salager, E., Deschamps, M., Grimaud, A., Johnson, L., Bruce, P. and Tarascon, J.-M. 
Role of electrolyte anions in the Na-O₂ battery: implications for NaO₂ solvation and the stability of the sodium solid electrolyte interphase in glyme-ethers
Chemistry of Materials, 29, 6066-6075, 2017

Yang, C., Fontaine, O., Tarascon, J.-M. and Grimaud, A. 
Chemical recognition of active oxygen species on the surface of oxygen evolution reaction electrocatalysts
Angewandte Chemie International Edition, 56, 8652-8656, 2017

Blazquez-Alcover, I., Rousse, G., Alves Dalla Corte, D., Badot, J.C., Grimaud, A., Rozier, P. and Tarascon, J.-M. 
Improving ionic conductivity by Mg-doping of A₂SnO₃ (A = Li⁺, Na⁺)
Solid State Ionics, 308, 16-21, 2017

Yang, C. and Grimaud A. 
Factors controlling the redox activity of oxygen in perovskites: from theory to application for catalytic reactions
Catalysts, 7, 149, 2017

Grimaud, A. 
Batteries: beyond intercalation and conversion
Nature Energy, 2, 17003, 2017

Azaceta, E., Lutz, L., Grimaud, A., Vicent-Luna, J. M., Hamad, S., Yate, L., Cabanero, G., Grande, H.-J., Anta, J. A., Tarascon, J.-M. and Tena-Zaera, R. 
Electrochemical reduction of oxygen in aprotic ionic liquids containing metal cations: Na-O₂ system case study
ChemSusChem, 107, 1616-1623, 2017

Yin, W., Grimaud, A., Lepoivre, F., Yang, C. and Tarascon, J.-M. 
Chemical vs electrochemical formation of Li₂CO₃ as a discharge product in Li-O₂/CO₂ batteries by controlling the superoxide intermediate
Journal of Physical Chemistry Letters, 8(1), 214-222, 2017

Grimaud, A., Demortière, A., Saubanère, M., Dachraoui, W., Duchamp, M., Doublet, M.-L. and Tarascon J.-M. 
Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction
Nature Energy, 2, art. no. 16189, 2017

2016

Lutz, L, Yin, W., Grimaud, A., Alves Dalla Corte, D., Tang, M., Johnson, L., Azaceta, E., Sarou-Kanian, V., Naylor, A.J., Hamad, S., Anta, J.A., Salager, E., Tena-Zaera, R., Bruce, P. and Tarascon J.-M. 
High capacity Na-O₂ batteries – Understanding the key parameters for solution-mediated discharge
Journal of Physical Chemistry C, 120(36), 20068-20076, 2016

Grimaud, A. and Tarascon, J.-M. 
Batteries: Evolution and vision
L’actualité chimique, 408-409, July 2016

Lepoivre, F., Grimaud, A., Larcher, D. and Tarascon J.-M. 
Long-time and reliable gas monitoring in Li-O₂ batteries via a Swagelock derived electrochemical cell
Journal of the Electrochemical Society, 163(6), A923-A929, 2016

Grimaud, A., Hong, W.T., Shao-Horn, Y. and Tarascon, J.-M. 
Anionic redox processes for electrochemical devices
Nature Materials, 15, 121-126, 2016

Prior

23.   Han, B., ^# Grimaud, A., ^# Giordano, L., Hong, W.T., Diaz-Morales, O., Lee, Y.-L., Hwang, J., Nenian, C., Stoerzinger, K., Yang, W., Koper, M.T.M. and Shao-Horn, Y. Iron-based perovskites for catalyzing oxygen evolution reaction, Journal of Physical Chemistry C, 122, 8445-8454, 2018 (^# these authors contributed equally)

22.  Hong, W.T., Stoerzinger, K.A., Lee, Y.-L., Giordano, L., Grimaud, A., Johnson, A.M., Hwang, J., Crumlin, E.J., Yang, W. and Shao-Horn, Y., Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides, Energy and Environmental Science, 10, 2190-2200, 2017

21.  Grimaud, A., ^# Diaz-Morales, ^# O., Han, B., ^# Hong, W.T., Lee, Y.-L., Giordano, L., Stoerzinger, K., Koper, M.T.M. and Shao-Horn, Y. Activating lattice oxygen redox reactions in metal oxides to catalyze oxygen evolution, Nature Chemistry, 9, 457-465, 2017 (^# these authors contributed equally)

20.   Bachman, C.J.,^# Muy, S.,^# Grimaud, A.,^# Chang, H.-H., Pour, N., Lux, S., Paschos, O., Maglia, F., Lupart, S., Lamp, P., Giordano, L. and Shao-Horn, Y A review of inorganic solid-state electrolytes for lithium batteries : mechanisms and properties governing ion conduction, Chemical Reviews, 116, 140-162, 2016 (^# these authors contributed equally)

19.   Gauthier, M.,^# Carney, T. J.,^# Grimaud, A.,^# Giordano, L., Pour, N., Chang, H-H., Fenning, D. P., Pachos, O., Maglia, F., Lupart, S., Lamp, P. and Shao-Horn, Y. The electrode-electrolyte interface in Li-ion batteries: Current understanding and new insights, Journal of Physical Chemistry Letters, 6, 46-53-4672, 2015 (^# these authors contributed equally)

18.   Yao K. P. C., Risch M., Sayed S. Y. Lee Y.-L., Harding J. H., Grimaud A., Pour N., Xu Z., Zhou J., Mansour A., Bardé F. and Shao-Horn Y. Solid-state activation of Li₂O₂ oxidation kinetics and implications for Li-O₂ batteries, Energy and Environmental Science, 8, 2417-2426, 2015.

17.   Hong, W. T.; Risch, M.; Stoerzinger, K. A.; Grimaud, A.; Suntivich, J. and Shao-Horn, Y. Toward the rational design of transition metal oxides for oxygen electrocatalysts, Energy and Environmental Science, 8, 1404-1427, 2015.

16.   Lee, D., Lee, Y-L., Grimaud A., Hong, W. T., Biegalski M. D., Morgan D. and Shao-Horn Y. Enhanced oxygen surface exchange kinetics and stability on epitaxial La_0.8Sr_0.2CoO_3-δ thin films by La_0.8Sr_0.2MnO_3-δ decoration, Journal of Physical Chemistry C,  118, 14326, 2014.

15.   Lee, D.; Lee, Y-L.; Grimaud A.; Hong W. T.; Biegalski M. D.; Morgan D. and Shao-Horn Y, Strontium influence on the oxygen electrocatalysis of La_2-xSr_xNiO_4+d (0.0 < x_Sr < 1.0) thin films, Journal of Materials Chemistry A, 2, 6480, 2014.

14.   Yao K.P.C., Lu Y.-C., Amanchukwu, C. V.; Kwabi D. G.; Risch M.; Zhou J.; Grimaud A., Hammond P. T.; Barde F. and Shao-Horn Y., The influence of transition metal oxides on the kinetics of Li₂O₂ oxidation for Li-O₂ batteries: High activity of chromium oxides, Physical Chemistry Chemical Physics, 13, 2297-2304, 2014.

13.   Grimaud A., Carlton C.E., Risch M., Hong W.T., May K.J. and Shao-Horn, Y., Oxygen evolution activity and stability of Ba₆Mn₅O₁₆, Sr₄Mn₂CoO₉ and Sr₆Co₅O₁₅: The influence of transition metal coordination, Journal of the Physical Chemistry C, 117, 25926, 2013.

12.   Grimaud A., May K.J., Carlton C.E., Lee Y.-L., Risch M., Zhou J. and Shao-Horn Y., Double perovskite as a new family of highly active catalysts for oxygen evolution in alkaline solution, Nature Communications, 4, art. no. 2439, 2013. 

11.   Lee D., Grimaud A., Crumlin E.J., Mezghani K., Habib M.A., Feng Z., Hong W.T., Biegalski M.D., Christen H.M. and Shao-Horn, Y., Strain influence on oxygen electrocatalysis of the (100)-oriented epitaxial La₂NiO_4+d thin films at elevated temperatures, Journal of Physical Chemistry C, 117, 18789, 2013.

10.  Wang, L., Imashuku, S., Grimaud, A., Lee, D., Mezghani, K., Habib, M. A. and Shao-Horn, Y., Enhancing oxygen permeation of electronically short-circuited oxygen-ion conductors by decorating with mixed ionic-electronic conducting oxides, ECS Electrochemistry Letters 2, F77, 2013.

9.    Risch M., Grimaud A., May K.J., Stoerzinger K.A., Chen T.J., Mansour A.N. and Shao-Horn Y., Structural changes of cobalt-based perovskites upon water oxidation investigated by EXAFS, Journal of Physical Chemistry C, 117, 8628, 2013.

8.    Yao K.P.C., Kwabi D.G., Quinlan R.A., Mansour A.N., Grimaud A., Lee Y.-L., Lu Y.-C. and Shao-Horn, Y., Thermal stability of Li₂O₂ and Li₂O for Li-air batteries: In situ XRD and XPS studies, Journal of the Electrochemical Society, 160, A824-A831, 2013. 

7.     May K.J., Carlton C.E., Stoerzinger K.A., Risch M., Suntivich J., Lee Y-L., Grimaud A. and Shao-Horn Y., Influence of oxygen evolution during water oxidation on the surface of perovskite oxide catalysts, Journal of Physical Chemistry Letters, 3, 22, 2012.

6.     Grimaud A., Bassat, J.-M, Mauvy, F., Pollet, M. Wattiaux, A., Weill, F., Marrony, M. and Grenier, J.-C., Oxygen reduction reaction of PrBaCo_2-xFe_xO_5+d compounds as H⁺-SOFC cathode: Correlation with physical properties, Journal of Material Chemistry A, 2, 3594, 2014.

5.    Dailly J., Marrony M., Taillades G., Taillades-Jacquin M., Grimaud A., Mauvy F., Louradour E. and Salmi J., Evaluation of proton conducting BCY-based anode supporting cells by co-pressing method: Up-scaling, performances and durability, Journal of Power Sources, 255, 302, 2014. 

4.    Xia, T., Brüll, A., Grimaud, A., Fourcade, S., Mauvy, F., Zhao, H., Grenier J-C and Bassat, J-M. Optimization of the electrochemical performance of a Ni/Ce_0.9Gd_0.1O_2-d-impregnated La_0.57Sr_0.15TiO₃ anode in hydrogen, Solid State Sciences, 35, 1, 2014.

3.    Grimaud A., Mauvy F., Bassat J.-M., Fourcade S., Marrony M. and Grenier J.-C., Hydration and transport properties of the Pr_2-xSr_xNiO_4+d compounds as H⁺-SOFC cathode, Journal of Materials Chemistry, 22, 31, 2012.

2.    Grimaud A., Mauvy F., Bassat J.-M., Fourcade S., Rocheron L., Marrony M. and Grenier J.-C., Hydration properties and rate determining steps of the oxygen reduction reaction of perovskite-related oxides as H⁺-SOFC cathode, Journal of the Electrochemical Society, 159, 6, 2012.

1.   Grimaud A., Bassat J.-M., Mauvy F., Simon P., Canizares A., Rousseau B. and Grenier J.-C., Transport properties and in-situ Raman spectroscopy study of BaCe_0.9Y_0.1O_3-d as a function of water partial pressure, Solid State Ionics, 191, 24, 2011.